An initial review (PCET1) on proton-coupled electron transfer (PCET) by Huynh and Meyer
appeared in Chemical Reviews in 2007.(1) This is a follow-up on the original. It was …

At the core of many important energy conversion processes in chemistry and biology are
oxidation-reduction reactions in which both electrons and protons are transferred. An …

Despite the critical role Ru and Os complexes have played in the development of transition
metal dinitrogen chemistry, they have not been shown to mediate catalytic N2-to-NH3 …

An extensive survey of the occurrences and origins of both structural trans-effects (STEs)
and kinetic trans-effects (KTEs) in octahedral d-transition metal complexes is presented. This …

All higher life forms use oxygen and respiration as their primary energy source. The oxygen
comes from water by solar‐energy conversion in photosynthetic membranes. In green …

Conversion of ammonia into dinitrogen has attracted broad scientific interest in relation to
molecular models of the heterogeneous nitrogen fixation process, environmental treatment …

Compounds that contain a late transition metal-nitrogen multiple bond represent important
reactive intermediate species in many useful organic and inorganic transformations. In order …

There is a remarkable redox chemistry of higher oxidation state M (IV)− M (VI) polypyridyl
complexes of Ru and Os. They are accessible by proton loss and formation of oxo or nitrido …

Recent interest in skeletal editing necessitates the continued development of reagent
classes with the ability to transfer single atoms. Terminal transition metal nitrides hold …

A comprehensive mechanistic study of N2 activation and splitting into terminal nitride
ligands upon reduction of the rhenium dichloride complex [ReCl2 (PNP)] is presented (PNP …