This review covers diastereo-and enantiodivergent catalyzed reactions in acyclic and cyclic
systems using metal complexes or organocatalysts. Among them, nucleophilic addition to …

Chiral molecules containing asymmetric carbon centers bonded with nitrogen are ubiquitous
in nature and also form important structural fragments in both natural and man-made …

Active without activation: In an inexpensive and atom‐economical approach to C H bond
functionalization, a cationic CoIII complex (see scheme) was used to generate nucleophilic …

In this critical review, the progress in catalytic asymmetric synthesis of β-amino acids is
discussed, covering the literature since 2002. The review treats transition metal catalysis …

Abstract α, α‐Diaryl (dialkyl) prolinol ethers constitute a potent organocatalyst family which
has been shown to be very general for a broad range of reactions involving enamine and …

The design and application of linked-BINOLs investigated in our group are reviewed. Linked-
BINOLs are a kind of semi-crown ether, thus they are flexible and applicable to metals …

We describe the first efficient, direct asymmetric Mannich reactions with malonates and N-
Boc aryl and alkyl imines by cooperative hydrogen-bonding catalysis with a cinchona …

Ohne Umschweife: Die Titelreaktion gelingt mit 5 Mol‐% des Katalysators 1 und ist binnen 1
h abgeschlossen. Die 2‐Alkyl‐und 2‐Aryl‐substituierten 3‐Pyrroline werden in guten …

Asymmetric alkynylation of both aromatic and aliphatic aldehydes using catalytic amounts of
In (III)/BINOL is described. Dual activation of both substrates due to the “bifunctional …

In this paper, indium (III) chloride was found to be a highly effective catalyst for the three-
component coupling reactions of aldehydes, alkynes, and amines (A3-coupling) via C− H …