Dynamic covalent bonds in polymeric materials
P Chakma, D Konkolewicz - Angewandte Chemie International …, 2019 - Wiley Online Library
Dynamic covalent bonds (DCBs) have received significant attention over the past decade.
These are covalent bonds that are capable of exchanging or switching between several …
These are covalent bonds that are capable of exchanging or switching between several …
Toward stimuli‐responsive dynamic thermosets through continuous development and improvements in covalent adaptable networks (CANs)
M Podgórski, BD Fairbanks, BE Kirkpatrick… - Advanced …, 2020 - Wiley Online Library
Covalent adaptable networks (CANs), unlike typical thermosets or other covalently
crosslinked networks, possess a unique, often dormant ability to activate one or more forms …
crosslinked networks, possess a unique, often dormant ability to activate one or more forms …
Adaptable crosslinks in polymeric materials: resolving the intersection of thermoplastics and thermosets
The classical division of polymeric materials into thermoplastics and thermosets based on
covalent network structure often implies that these categories are distinct and irreconcilable …
covalent network structure often implies that these categories are distinct and irreconcilable …
Dynamic covalent chemistry in polymer networks: a mechanistic perspective
JM Winne, L Leibler, FE Du Prez - Polymer Chemistry, 2019 - pubs.rsc.org
The incorporation of dynamic covalent linkages within and between polymer chains brings
new properties to classical thermosetting polymer formulations, in particular in terms of …
new properties to classical thermosetting polymer formulations, in particular in terms of …
Fast dynamic siloxane exchange mechanism for reshapable vitrimer composites
T Debsharma, V Amfilochiou… - Journal of the …, 2022 - ACS Publications
To develop siloxane-containing vitrimers with fast dynamic characteristics, different
mechanistic pathways have been investigated using a range of catalysts. In particular, one …
mechanistic pathways have been investigated using a range of catalysts. In particular, one …
Colorless, transparent, robust, and fast scratch‐self‐healing elastomers via a phase‐locked dynamic bonds design
Robust self‐healing thermoplastic elastomers are expected to have repeated healing
capability, remarkable mechanical properties, transparency, and superior toughness. The …
capability, remarkable mechanical properties, transparency, and superior toughness. The …
Functional epoxy vitrimers and composites
Y Yang, Y Xu, Y Ji, Y Wei - Progress in Materials Science, 2021 - Elsevier
From cars to airplanes, from household appliances to indoor ornaments, from biomedical
devices to factory equipment, epoxy resins have been deeply rooted in modern society. But …
devices to factory equipment, epoxy resins have been deeply rooted in modern society. But …
Dynamic bonds: adaptable timescales for responsive materials
SV Wanasinghe, OJ Dodo… - Angewandte Chemie, 2022 - Wiley Online Library
Dynamic bonds introduce unique properties such as self‐healing, recyclability, shape
memory, and malleability to polymers. Significant efforts have been made to synthesize a …
memory, and malleability to polymers. Significant efforts have been made to synthesize a …
Exchangeable liquid crystalline elastomers and their applications
This Review presents and discusses the current state of the art in “exchangeable liquid
crystalline elastomers”, that is, LCE materials utilizing dynamically cross-linked networks …
crystalline elastomers”, that is, LCE materials utilizing dynamically cross-linked networks …
On the welding of vitrimers: Chemistry, mechanics and applications
Linear chains in thermoplastics make them relatively weak in performance but inherently
weldable and recyclable. By contrast, thermosets with permanently crosslinked networks …
weldable and recyclable. By contrast, thermosets with permanently crosslinked networks …