Two synthetic approaches have until now been used to synthesize transition metal
complexes having a tridentate (pincer or tripod) PEP tetryl (E= Si, Ge, Sn) ligand. These …

Electron-rich late metals and electropositive main-group elements (metals and metalloids)
can be combined to provide an ambiphilic façade for exploring metal–ligand cooperation …

Bond activation and catalysis are central to the development of a sustainable energy system.
Frustrated Lewis Pairs have conceptually revolutionized the activation of inert chemical …

We report rhodium complexes bearing PAlP pincer ligands with an X-type aluminyl moiety.
IR spectroscopy and single-crystal X-ray diffraction analysis of a carbonyl complex exhibit …

The unexpectedly facile insertion of Rh or Ir into a B–Ph bond (reversible for Rh) converts a
borane/bis (phosphine) precursor into a boryl/bis (phosphine) PBP pincer ligand …

Four different [PSiP]-pincer ligands L1–L4 ((2-Ph2PC6H4) 2SiHR (R= H (L1) and Ph (L2))
and (2-i Pr2PC6H4) 2SiHR′(R′= Ph (L3) and H (L4)) were used to investigate the effect of …

Iron–and cobalt–dinitrogen complexes bearing PSiP‐type pincer ligands are newly
designed and prepared, on the basis of our previous proposal that iron–and cobalt …

Six silyl cobalt (III) hydrides 1–6 with [PSiP] pincer ligands having different substituents at the
P and Si atoms ([(2-Ph2PC6H4) 2MeSiCo (H)(Cl)(PMe3)](1),[(2-Ph2PC6H4) 2HSiCo …

Given the critical importance of novel ligand development for transition-metal (TM) catalysis,
as well as the resurgence of the field of organosilicon chemistry and silyl ligands, to …

A PGeP pincer-type germylene, Ge (NCH2PtBu2) 2C6H4, which contains two phosphane
groups hanging from the N atoms of an N-heterocyclic germylene fragment, has been …