The interest in synthesizing heterocycles has always been enormous. The literature contains
a variety of synthetic approaches to the heterocycle ring structures, much of which has been …

A copper‐catalyzed silylation of propargyl dichlorides was developed to access chloro‐
substituted allenylsilanes under mild reaction conditions. Moreover, enantioenriched chloro …

Indium (III) halides catalyze efficiently the intramolecular hydroarylation (IMHA) of aryl
propargyl ethers. The reaction proceeds regioselectively with terminal and internal alkynes …

Appropriately substituted nonracemic allyl alcohols, readily prepared from the
corresponding enones by application of the CBS methodology, were converted to optically …

A concise, convergent synthesis of (±)-frondosin B has been developed based on the
application of a Stille–Heck reaction sequence of 2-chloro-5-methoxybenzo [b] furan-3-yl …

o-Bromo (propa-1, 2-dien-1-yl) arenes exhibit novel and orthogonal reactivity under Pd
catalysis in the presence of secondary amines to form enamines (concerted Pd insertion …

Abstract The total synthesis of (+)‐awajanomycin has been achieved by asymmetric
allylboration of a vicinal tricarbonyl compound as the key step. A substrate‐controlled …

Sequential and one-pot Stille–Heck and Heck–Stille reaction processes have been invoked
to give divergent access to polycyclic ring systems. Both reaction conditions and substrate …

The first synthesis of diterpenoid eunicellane skeletons incorporating a 1, 3-cyclohexadiene
moiety is presented. Key step is a low-valent titanium-induced pinacol cyclization that …

The article discusses a study which investigated the performance of electron-rich and bulky
phosphines in the reaction of o-bromotoluene with pent-2-yn-1-ol. The desired product in …