Polymers without petrochemicals: sustainable routes to conventional monomers

G Hayes, M Laurel, D MacKinnon, T Zhao… - Chemical …, 2022 - ACS Publications
Access to a wide range of plastic materials has been rationalized by the increased demand
from growing populations and the development of high-throughput production systems …

Renewable polyurethanes from sustainable biological precursors

TA Phung Hai, M Tessman, N Neelakantan… - …, 2021 - ACS Publications
Due to the depletion of fossil fuels, higher oil prices, and greenhouse gas emissions, the
scientific community has been conducting an ongoing search for viable renewable …

Sustainable productions of organic acids and their derivatives from biomass via selective oxidative cleavage of C–C bond

M Wang, J Ma, H Liu, N Luo, Z Zhao, F Wang - ACS Catalysis, 2018 - ACS Publications
Biomass is renewable and the most abundant carbon resource, and it shows great potential
for sustainable production of chemicals in the future. With respect to limited fossil reserves …

Hydrogen peroxide as an oxidant in biomass-to-chemical processes of industrial interest

SP Teong, X Li, Y Zhang - Green Chemistry, 2019 - pubs.rsc.org
Production of chemicals and fuels from renewable biomass is a hot topic of current research.
Theoretically, most of the fuels and chemicals from petroleum resources can be synthesised …

Flexible polyurethanes, renewable fuels, and flavorings from a microalgae oil waste stream

TAP Hai, N Neelakantan, M Tessman, SD Sherman… - Green …, 2020 - pubs.rsc.org
Renewable polymers have become an important focus in next-generation materials, and
algae biomass offers an environmentally low-impact feedstock that can serve multiple uses …

Homogeneous catalysis and heterogeneous recycling: a simple Zn (ii) catalyst for green fatty acid esterification

M Melchiorre, ME Cucciolito, M Di Serio… - ACS Sustainable …, 2021 - ACS Publications
This work describes the use of simple zinc (II) salts (ZnCl2, ZnCO3, Zn (OAc) 2, ZnO, Zn
(ClO4) 2, Zn (TfO) 2, and Zn (BF4) 2) as effective catalysts for the esterification of fatty acids …

Iron (III) complexes for highly efficient and sustainable ketalization of glycerol: a combined experimental and theoretical study

R Esposito, U Raucci, ME Cucciolito, R Di Guida… - ACS …, 2019 - ACS Publications
The growing production of biodiesel as a promising alternative and renewable fuel led as
the main problem the dramatic increase of its by-product: glycerol. Different strategies for …

Solvent-free transesterification of methyl levulinate and esterification of levulinic acid catalyzed by a homogeneous iron (III) dimer complex

M Melchiorre, R Amendola, V Benessere… - Molecular …, 2020 - Elsevier
Levulinic acid esters MeC (O) CH 2 CH 2 CO 2 R (LAE) are emerging bio-based chemicals
used as solvents, additives and plasticizers. In this work a variety of levulinates (R= n-butyl …

Properties of novel polyesters made from renewable 1, 4‐pentanediol

BM Stadler, A Brandt, A Kux, H Beck… - …, 2020 - Wiley Online Library
Novel polyester polyols were prepared in high yields from biobased 1, 4‐pentanediol
catalyzed by non‐toxic phosphoric acid without using a solvent. These oligomers are …

Emerging catalysis in biomass valorisation: Simple Zn (II) catalysts for fatty acids esterification and transesterification

R Esposito, M Melchiorre, A Annunziata… - …, 2020 - Wiley Online Library
The growing concern about global warming and the consumption of fossil fuels has driven in
recent decades the use of biomass as a renewable feedstock. In this context, vegetable oils …