Aliphatic azides are a versatile class of compounds found in a variety of biologically active
pharmaceuticals. These compounds are also recognized as useful precursors for the …

The generation of azide radical (N3˙) occurs from its precursors primarily via a single
electron transfer (SET) process or homolytic cleavage by chemical methods or advanced …

The azido group is found in large numbers of natural products, drugs, biochemicals and
materials and to date, many elegant and useful methods for the synthesis of organic azides …

Unprotected, primary 2-azidoamines are versatile precursors to vicinal diamines, which are
among the most common motifs in biologically active compounds. Herein, we report their …

As the aromatic tryptophan (Trp) side chain plays a pivotal role in influencing the structure
and function of peptides and proteins, it has become an attractive target for the late‐stage …

Vinyl sulfones are privileged motifs for assembling prevalent biologically active molecules
and represent “gateway functional groups” in medicinal chemistry and drug discovery …

The first example of a photoinduced rapid multicomponent cascade reaction of
aryldiazonium salts with unactivated alkenes and trimethylsilyl azide (TMSN3) under oxidant …

Disclosed here is a catalytic asymmetric azidation reaction for the efficient synthesis of α-
azido ketones bearing a labile tertiary stereocenter. With a superb chiral squaramide …

Visible light-driven azidation of vinyl arenes with azidobenziodoxole as the azidating agent
was investigated in acetonitrile by using Cu (I)(phenanthroline) 2 complex [Cu (dap) 2] PF6 …

The selective successive addition of azide (• N3) and N-oxyl radicals to alkenes is
demonstrated, despite each of the two radicals being known to attack C═ C bonds and the …