Two-dimensional metal-organic framework materials: synthesis, structures, properties and applications

G Chakraborty, IH Park, R Medishetty… - Chemical Reviews, 2021 - ACS Publications
Among the recent developments in metal-organic frameworks (MOFs), porous layered
coordination polymers (CPs) have garnered attention due to their modular nature and …

Photoreactive crystals exhibiting [2+ 2] photocycloaddition reaction and dynamic effects

BB Rath, JJ Vittal - Accounts of Chemical Research, 2022 - ACS Publications
Conspectus Conducting a reaction in the solid state eliminates the usage of solvents. If such
reactions are conducted in a single-crystal to single-crystal (SCSC) fashion, then structural …

Coordination change, lability and hemilability in metal–organic frameworks

RE Morris, L Brammer - Chemical Society Reviews, 2017 - pubs.rsc.org
Metal–organic frameworks (MOFs) are some of the most exciting materials in current
science. Their utility and diversity of applications depends on a combination of their …

Pillar-layered MOFs: functionality, interpenetration, flexibility and applications

F ZareKarizi, M Joharian, A Morsali - Journal of Materials Chemistry A, 2018 - pubs.rsc.org
Pillar-layered metal–organic frameworks (MOFs) are among the most interesting research
areas in crystalline materials. Due to the great number of reports related to pillar-layered …

A controllable gate effect in cobalt (II) organic frameworks by reversible structure transformations

Q Chen, Z Chang, WC Song, H Song… - Angewandte …, 2013 - Wiley Online Library
Materials that show reversible structure transformation and a characteristic response toward
specific external stimuli are vitally important for applications in sensing, molecular capture …

Substitution reactions in metal–organic frameworks and metal–organic polyhedra

Y Han, JR Li, Y Xie, G Guo - Chemical Society Reviews, 2014 - pubs.rsc.org
Substitution reaction, as one of the most powerful and efficient chemical reactions, has been
widely used in various syntheses, including those for the design and preparation of …

Approaches for synthesizing breathing MOFs by exploiting dimensional rigidity

CR Murdock, BC Hughes, Z Lu, DM Jenkins - Coordination Chemistry …, 2014 - Elsevier
A subclass of metal-organic frameworks (MOFs) undergoes a “breathing” phenomenon
which is a reversible flexing of the framework as a function of adsorbed guest. The existence …

Solid-state polymerisation via [2+ 2] cycloaddition reaction involving coordination polymers

R Medishetty, IH Park, SS Lee, JJ Vittal - Chemical Communications, 2016 - pubs.rsc.org
Highly crystalline metal ions containing organic polymers are potentially useful to
manipulate the magnetic and optical properties to make advanced multifunctional materials …

Distortional supramolecular isomers of polyrotaxane coordination polymers: photoreactivity and sensing of nitro compounds

IH Park, R Medishetty, JY Kim, SS Lee… - Angewandte …, 2014 - Wiley Online Library
Distortional isomers, or bond‐stretch isomers, differ only in the length of one or more bonds,
which is due to crystallographic disorder in most cases. The term distortional isomerism is …

Controlling mechano-and seeding-triggered single-crystal-to-single-crystal phase transition: molecular domino with a disconnection of aurophilic bonds.

T Seki, K Sakurada, H Ito - Angewandte Chemie, 2013 - search.ebscohost.com
Organic and organometallic materials with mechano-responsive properties have been
intensively studied because these materials can potentially be used in various applications …