The electron is a catalyst

A Studer, DP Curran - Nature chemistry, 2014 - nature.com
The electron is an efficient catalyst for conducting various types of radical cascade reaction
that proceed by way of radical and radical ion intermediates. But because electrons are …

Occurrence, biogenesis, and synthesis of biologically active carbazole alkaloids

AW Schmidt, KR Reddy, HJ Knölker - Chemical reviews, 2012 - ACS Publications
Since our previous review, 1 there has been a tremendous development in the field of
carbazole alkaloids. New synthetic methodologies have been developed, existing …

Widespread antioxidants during storm events could serve as precursors of regulated, priority, and new disinfection byproducts

W Yang, C Fang, Y Hong, ZF Zhang… - … Science & Technology, 2024 - ACS Publications
Widely used antioxidants can enter the environment via urban stormwater systems and form
disinfection byproducts (DBPs) during chlorination in downstream drinking water processes …

Visible Light Induced Metal-Free Carbene N-Carbazolation

C Empel, FW Patureau, RM Koenigs - The Journal of Organic …, 2019 - ACS Publications
Metal-free N–H functionalization reactions represent an important strategy for sustainable C–
N coupling reactions. In this report, we describe the visible light photolysis of aryl …

Tunable hemilabile ligands for adaptive transition metal complexes

R Lindner, B van den Bosch, M Lutz, JNH Reek… - …, 2011 - ACS Publications
A new family of monoanionic hemilabile ligands L1H− L3H with a PNN donor set has been
developed, based on Pd-catalyzed C− N bond formation and straightforward …

Size and stability modulation of Pd nanoparticles on porous hypercrosslinked ionic polymer for heterogeneous aerobic oxidative coupling of diaryl ether

K Wang, W Cui, Z Bian, Y Liu, S Jiang, Y Zhou… - Applied Catalysis B …, 2021 - Elsevier
Oxidative coupling of two aromatic Csingle bondH bonds is normally catalyzed by Pd (II)
species involving an electrophilic attacking step. Herein, we demonstrated surprisingly the …

Energy Counterbalance to Harness Photoinduced Structural Planarization of Dibenzo[b,f]azepines toward Thermal Reversibility

Y Chen, SM Tseng, KH Chang… - Journal of the American …, 2022 - ACS Publications
In sharp contrast to most photoinduced structural planarization (PISP) phenomena, which
are highly exergonic and irreversible processes, we report here a series of a new class of …

Synthesis of Carbazoles via One‐Pot Copper‐Catalyzed Amine Insertion into Cyclic Diphenyleneiodoniums as a Strategy to Generate a Drug‐Like Chemical Library

D Zhu, Q Liu, B Luo, M Chen, R Pi… - … Synthesis & Catalysis, 2013 - Wiley Online Library
Carbazoles have attracted high interest among synthetic chemists due to their unique
structural features and potential pharmacological activities. Compared to linear …

Nonprecious metals catalyzing Hydroamination and C–N coupling reactions

SM Coman, VI Parvulescu - Organic Process Research & …, 2015 - ACS Publications
This review highlights the recent achievements in replacing precious-metal-based catalysts
with nonprecious-metal-based catalysts in two important syntheses: hydroamination and C …

Silver (I)-catalyzed dearomatization of alkyne-tethered indoles: Divergent synthesis of spirocyclic indolenines and carbazoles

MJ James, RE Clubley, KY Palate, TJ Procter… - Organic …, 2015 - ACS Publications
A high-yielding, divergent approach to generate either spirocyclic indolenines or carbazoles
from a common indole-tethered propargyl alcohol precursor is described, with mechanistic …