Group 4 complexes as catalysts for the transformation of CO2 into polycarbonates and cyclic carbonates

M Mandal - Journal of Organometallic Chemistry, 2020 - Elsevier
Group 4 complexes, especially titanium, are soil compostable and nontoxic to the soil
environment. Hence, group 4 complexes as catalysts are the perfect alternative for the …

Recently developed applications for natural hydrophilic polymers

K Halake, HJ Kim, M Birajdar, BS Kim, H Bae… - Journal of industrial and …, 2016 - Elsevier
Natural hydrophilic polymers have been utilized for a variety of applications, ranging from
the food industry to the coatings industry. However, recent social needs have demanded …

Enhancing catalytic strategy for cyclic carbonates synthesized from CO2 and epoxides by using cobaloxime-based double complex salts as catalysts

A Alhafez, E Aytar, A Kilic - Journal of CO2 Utilization, 2022 - Elsevier
In this study, the novel neutral cobaloximes and corresponding to different cobaloxime-
based double complex salts were prepared and for the first time evaluated as an efficient …

The sustainable catalytic conversion of CO2 into value-added chemicals by using cobaloxime-based double complex salts as efficient and solvent-free catalysts

A Kilic, A Alhafez, E Aytar, R Soylemez - Inorganica Chimica Acta, 2023 - Elsevier
Cobalt (III)-based catalysts for CO 2 fixation are widely applied for the synthesis of cyclic
carbonates from epoxides and CO 2 under suitable and solvent-free conditions. Inspired by …

Functional group effects on a metal-organic framework catalyst for CO2 cycloaddition

J Noh, Y Kim, H Park, J Lee, M Yoon, MH Park… - Journal of Industrial and …, 2018 - Elsevier
A variety of metal-organic frameworks (MOFs) have been reported as efficient catalysts for
CO 2 fixation reactions, such as cycloaddition to cyclic carbonates. The permanent porosity …

Synthesis and effective catalytic performance in cycloaddition reactions with CO 2 of boronate esters versus N-heterocyclic carbene (NHC)-stabilized boronate esters

A Kilic, B Sobay, E Aytar, R Söylemez - Sustainable Energy & Fuels, 2020 - pubs.rsc.org
A series of boronate esters (1–3) and N-heterocyclic carbene (NHC)-stabilized boronate
esters (4–6) were synthesized and characterized by various spectroscopic techniques …

Synthesis of half-sandwich ruthenium (II) and iridium (III) complexes containing imidazole-based phosphinite ligands and their use in catalytic transfer hydrogenation …

U Işık, N Meriç, C Kayan, A Kılıç, Y Belyankova… - Journal of …, 2023 - Elsevier
Abstract Two ionic liquids (3-(3‑chloro-2-hydroxypropyl)-1-vinyl-1H-imidazol-3-ium chloride
and 3-(3‑chloro-2-hydroxypropyl)-1‑butyl‑1H-imidazol-3-ium chloride) were prepared from …

Catalysis Conversion of Carbon Dioxide and Epoxides by Tetrahydroxydiboron To Prepare Cyclic Carbonates

Y Luo, F Chen, H Zhang, J Liu… - The Journal of Organic …, 2023 - ACS Publications
A binary catalytic system comprising tetrahydroxydiboron and tetrabutylammonium iodide
(TBAI) was used to catalyze the cycloaddition of carbon dioxide (CO2) with epoxides. The …

Highly active dinuclear cobalt complexes for solvent-free cycloaddition of CO 2 to epoxides at ambient pressure

ZAK Khattak, HA Younus, N Ahmad, H Ullah… - Chemical …, 2019 - pubs.rsc.org
Dinuclear Co-based catalysts are used for the coupling reaction of epoxides and CO2 in the
presence of a cocatalyst. The easily recyclable catalysts efficiently complete the coupling of …

Isonicotinate-Zn (ii)/Cd (ii) bridged dicobaloximes: synthesis, characterization and electrocatalytic proton reduction studies

JK Yadav, A Mishra, GK Mishra, SK Pal… - New Journal of …, 2023 - pubs.rsc.org
Herein, we present the synthesis of two new dicobaloxime complexes,[{ClCo (dmgH) 2 (4-
PyCOO)} 2Zn (DMF) 2](1) and [{ClCo (dmgH) 2 (4-PyCOO)} 2Cd (H2O) 3 (DMF)]. 4H2O (2) …