Structure and valency of a cobalt− phosphate water oxidation catalyst determined by in situ X-ray spectroscopy
A water oxidation catalyst generated via electrodeposition from aqueous solutions
containing phosphate and Co2+ (Co− Pi) has been studied by in situ X-ray absorption …
containing phosphate and Co2+ (Co− Pi) has been studied by in situ X-ray absorption …
A Co4O4 “Cubane” Water Oxidation Catalyst Inspired by Photosynthesis
NS McCool, DM Robinson, JE Sheats… - Journal of the …, 2011 - ACS Publications
Herein we describe the molecular Co4O4 cubane complex Co4O4 (OAc) 4 (py) 4 (1), which
catalyzes efficient water oxidizing activity when powered by a standard photochemical …
catalyzes efficient water oxidizing activity when powered by a standard photochemical …
Catalytic oxygen evolution by cobalt oxido thin films
DK Bediako, AM Ullman, DG Nocera - Solar energy for fuels, 2016 - Springer
The contemporary demand to generate fuels from solar energy has stimulated intense effort
to develop water splitting catalysts that can be coupled to light-absorbing materials. Cobalt …
to develop water splitting catalysts that can be coupled to light-absorbing materials. Cobalt …
Polynuclear cobalt complexes as catalysts for light-driven water oxidation: A review of recent advances
DS Nesterov, OV Nesterova - Catalysts, 2018 - mdpi.com
Photochemical water oxidation, as a half-reaction of water splitting, represents a great
challenge towards the construction of artificial photosynthetic systems. Complexes of first …
challenge towards the construction of artificial photosynthetic systems. Complexes of first …
Electronic Structure Description of a [Co(III)3Co(IV)O4] Cluster: A Model for the Paramagnetic Intermediate in Cobalt-Catalyzed Water Oxidation
Multifrequency electron paramagnetic resonace (EPR) spectroscopy and electronic structure
calculations were performed on [Co4O4 (C5H5N) 4 (CH3CO2) 4]+(1+), a cobalt tetramer …
calculations were performed on [Co4O4 (C5H5N) 4 (CH3CO2) 4]+(1+), a cobalt tetramer …
X-ray Spectroscopic Characterization of Co(IV) and Metal–Metal Interactions in Co4O4: Electronic Structure Contributions to the Formation of High-Valent States …
The formation of high-valent states is a key factor in making highly active transition-metal-
based catalysts of the oxygen evolution reaction (OER). These high oxidation states will be …
based catalysts of the oxygen evolution reaction (OER). These high oxidation states will be …
Water Oxidation by the [Co4O4(OAc)4(py)4]+ Cubium is Initiated by OH– Addition
The cobalt cubium Co4O4 (OAc) 4 (py) 4 (ClO4)(1A+) containing the mixed valence [Co4O4]
5+ core is shown by multiple spectroscopic methods to react with hydroxide (OH–) but not …
5+ core is shown by multiple spectroscopic methods to react with hydroxide (OH–) but not …
Oxidovanadium complexes with tridentate aroylhydrazone as catalyst precursors for solvent-free microwave-assisted oxidation of alcohols
Aroylhydrazone oxidovanadium compounds, viz. the oxidoethoxidovanadium (V)[VO (OEt)
L](1)(H 2 L= salicylaldehyde-2-hydroxybenzoylhydrazone), the salt like dioxidovanadium …
L](1)(H 2 L= salicylaldehyde-2-hydroxybenzoylhydrazone), the salt like dioxidovanadium …
Solvent-free aerobic selective oxidation of benzyl alcohol over La-Co bimetallic catalyst: A kinetic study
W Wang, R Wang, X Jiang, ZH He, K Wang… - Applied Catalysis A …, 2022 - Elsevier
It is desirable but challenging to explore non-noble metal based catalyst for the solvent-free
aerobic oxidation of benzyl alcohol to benzaldehyde. La y Co 1 O x was prepared through a …
aerobic oxidation of benzyl alcohol to benzaldehyde. La y Co 1 O x was prepared through a …
Copper–organic frameworks assembled from in situ generated 5-(4-pyridyl) tetrazole building blocks: Synthesis, structural features, topological analysis and catalytic …
Two new metal–organic compounds {[Cu3 (μ3-4-ptz) 4 (μ2-N3) 2 (DMF) 2](DMF) 2} n (1)
and {[Cu (4-ptz) 2 (H2O) 2]} n (2){4-ptz= 5-(4-pyridyl) tetrazolate} with 3D and 2D …
and {[Cu (4-ptz) 2 (H2O) 2]} n (2){4-ptz= 5-(4-pyridyl) tetrazolate} with 3D and 2D …