Transition metals-catalyzed amination of biomass feedstocks for sustainable construction of N-heterocycles

Q Yan, X Wu, H Jiang, H Wang, F Xu, H Li… - Coordination Chemistry …, 2024 - Elsevier
Transition metals, which are of diversity in their bonding orbitals, have a variety of significant
oxidation states and more complex chemical properties compared to the main group metals …

Recent advances in sustainable synthesis of N-heterocycles following acceptorless dehydrogenative coupling protocol using alcohols

M Maji, D Panja, I Borthakur, S Kundu - Organic Chemistry Frontiers, 2021 - pubs.rsc.org
The synthesis of heterocycles is an emerging area of chemical research considering their
high importance in pharmaceuticals, material chemistry, and natural product synthesis. The …

Iridium supported on porous polypyridine-oxadiazole as high-activity and recyclable catalyst for the borrowing hydrogen reaction

J Li, A Mao, W Yao, H Zhu, D Wang - Green Chemistry, 2022 - pubs.rsc.org
Homogenization of heterogeneous catalysts is a valuable and interesting research topic.
Porous polypyridine-oxadiazole (PPO), as not only a carrier but also a ligand, was designed …

Well-defined phosphine-free manganese (II)-complex-catalyzed synthesis of quinolines, pyrroles, and pyridines

A Maji, S Gupta, M Maji, S Kundu - The Journal of Organic …, 2022 - ACS Publications
Herein, we report a simple, phosphine-free, and inexpensive catalytic system based on a
manganese (II) complex for synthesizing different important N-heterocycles such as …

N-Alkylation of Amines by C1–C10 Aliphatic Alcohols Using A Well-Defined Ru(II)-Catalyst. A Metal–Ligand Cooperative Approach

AK Guin, S Pal, S Chakraborty… - The Journal of …, 2023 - ACS Publications
A Ru (II)-catalyzed efficient and selective N-alkylation of amines by C1–C10 aliphatic
alcohols is reported. The catalyst [Ru (L1a)(PPh3) Cl2](1a) bearing a tridentate redox-active …

Metal–organic framework-derived CoN x nanoparticles on N-doped carbon for selective N-alkylation of aniline

V Vyas, P Maurya, A Indra - Chemical Science, 2023 - pubs.rsc.org
N-alkylation of anilines by alcohols can be used as an efficient strategy to synthesise a wide
range of secondary amines. In this respect, a hydrogen borrowing methodology has been …

Multifunctional catalysis of nanosheet defective molybdenum sulfide basal planes for tandem reactions involving alcohols and molecular hydrogen

M Rodenes, F Dhaeyere, S Martín… - ACS Sustainable …, 2023 - ACS Publications
Establishing tandem catalytic synthetic strategies based on the use of readily available,
stable, and renewable feedstocks is of great significant for the sustainable advancement of …

Dehydrogenative synthesis of quinolines and quinazolines via ligand-free cobalt-catalyzed cyclization of 2-aminoaryl alcohols with ketones or nitriles

Z Hao, X Zhou, Z Ma, C Zhang, Z Han… - The Journal of Organic …, 2022 - ACS Publications
We present a convenient and efficient protocol to synthesize quinolines and quinazolines in
one pot under mild conditions. A variety of substituted quinolines were synthesized in good …

Borrowing Hydrogen and Acceptorless Dehydrogenative Coupling in the Multicomponent Synthesis of N‐Heterocycles: A Comparison between Base and Noble Metal …

N Hofmann, KC Hultzsch - European Journal of Organic …, 2021 - Wiley Online Library
Acceptorless dehydrogenative coupling reactions (ADC) and hydrogen transfer strategies
(HT) provide a powerful tool in the multicomponent formation of N‐heterocycles. A broad …

Manganese (I)-catalyzed sustainable synthesis of quinoxaline and quinazoline derivatives with the liberation of dihydrogen

A Mondal, MK Sahoo, M Subaramanian… - The Journal of …, 2020 - ACS Publications
Direct synthesis of N-heterocycles via the acceptorless dehydrogenative coupling is very
challenging and scarcely reported under 3d transition-metal catalysis. Here, we have …