Transition metals-catalyzed amination of biomass feedstocks for sustainable construction of N-heterocycles
Q Yan, X Wu, H Jiang, H Wang, F Xu, H Li… - Coordination Chemistry …, 2024 - Elsevier
Transition metals, which are of diversity in their bonding orbitals, have a variety of significant
oxidation states and more complex chemical properties compared to the main group metals …
oxidation states and more complex chemical properties compared to the main group metals …
Recent advances in sustainable synthesis of N-heterocycles following acceptorless dehydrogenative coupling protocol using alcohols
The synthesis of heterocycles is an emerging area of chemical research considering their
high importance in pharmaceuticals, material chemistry, and natural product synthesis. The …
high importance in pharmaceuticals, material chemistry, and natural product synthesis. The …
Iridium supported on porous polypyridine-oxadiazole as high-activity and recyclable catalyst for the borrowing hydrogen reaction
J Li, A Mao, W Yao, H Zhu, D Wang - Green Chemistry, 2022 - pubs.rsc.org
Homogenization of heterogeneous catalysts is a valuable and interesting research topic.
Porous polypyridine-oxadiazole (PPO), as not only a carrier but also a ligand, was designed …
Porous polypyridine-oxadiazole (PPO), as not only a carrier but also a ligand, was designed …
Well-defined phosphine-free manganese (II)-complex-catalyzed synthesis of quinolines, pyrroles, and pyridines
Herein, we report a simple, phosphine-free, and inexpensive catalytic system based on a
manganese (II) complex for synthesizing different important N-heterocycles such as …
manganese (II) complex for synthesizing different important N-heterocycles such as …
N-Alkylation of Amines by C1–C10 Aliphatic Alcohols Using A Well-Defined Ru(II)-Catalyst. A Metal–Ligand Cooperative Approach
A Ru (II)-catalyzed efficient and selective N-alkylation of amines by C1–C10 aliphatic
alcohols is reported. The catalyst [Ru (L1a)(PPh3) Cl2](1a) bearing a tridentate redox-active …
alcohols is reported. The catalyst [Ru (L1a)(PPh3) Cl2](1a) bearing a tridentate redox-active …
Metal–organic framework-derived CoN x nanoparticles on N-doped carbon for selective N-alkylation of aniline
N-alkylation of anilines by alcohols can be used as an efficient strategy to synthesise a wide
range of secondary amines. In this respect, a hydrogen borrowing methodology has been …
range of secondary amines. In this respect, a hydrogen borrowing methodology has been …
Multifunctional catalysis of nanosheet defective molybdenum sulfide basal planes for tandem reactions involving alcohols and molecular hydrogen
M Rodenes, F Dhaeyere, S Martín… - ACS Sustainable …, 2023 - ACS Publications
Establishing tandem catalytic synthetic strategies based on the use of readily available,
stable, and renewable feedstocks is of great significant for the sustainable advancement of …
stable, and renewable feedstocks is of great significant for the sustainable advancement of …
Dehydrogenative synthesis of quinolines and quinazolines via ligand-free cobalt-catalyzed cyclization of 2-aminoaryl alcohols with ketones or nitriles
Z Hao, X Zhou, Z Ma, C Zhang, Z Han… - The Journal of Organic …, 2022 - ACS Publications
We present a convenient and efficient protocol to synthesize quinolines and quinazolines in
one pot under mild conditions. A variety of substituted quinolines were synthesized in good …
one pot under mild conditions. A variety of substituted quinolines were synthesized in good …
Borrowing Hydrogen and Acceptorless Dehydrogenative Coupling in the Multicomponent Synthesis of N‐Heterocycles: A Comparison between Base and Noble Metal …
N Hofmann, KC Hultzsch - European Journal of Organic …, 2021 - Wiley Online Library
Acceptorless dehydrogenative coupling reactions (ADC) and hydrogen transfer strategies
(HT) provide a powerful tool in the multicomponent formation of N‐heterocycles. A broad …
(HT) provide a powerful tool in the multicomponent formation of N‐heterocycles. A broad …
Manganese (I)-catalyzed sustainable synthesis of quinoxaline and quinazoline derivatives with the liberation of dihydrogen
Direct synthesis of N-heterocycles via the acceptorless dehydrogenative coupling is very
challenging and scarcely reported under 3d transition-metal catalysis. Here, we have …
challenging and scarcely reported under 3d transition-metal catalysis. Here, we have …