[1, 2]-Phospha-Brook rearrangement entails the generation of α-oxygenated carbanions via
the umpolung process. Recently, these anionic species have been widely utilized for several …

Abstract The [1, 2]‐phospha‐Brook rearrangement involves the migration of the
dialkoxyphosphoryl moiety of the alkoxide of an α‐hydroxyphosphonate from carbon to …

The multicomponent catalytic asymmetric Pudovik addition/[1, 2]-phospha-Brook
rearrangement/Michael reaction sequence of isatins, phosphites, and 4-oxobutenoates was …

Pudovik addition/[1, 2]-phospha-Brook rearrangement as an efficient tool for generation of
anionic nucleophiles is an attractive strategy for the construction of C–C bonds in organic …

The addition of α-ketoamide to p-quinone methide initiated by dialkylphosphite in the
presence of organic base 1, 8-diazabicyclo (5.4. 0) undec-7-ene (DBU) is explored …

A highly regio-and diastereoselective approach for the synthesis of phosphate substituted
dihydrocoumarins via Brønsted base catalyzed [1, 2]-phospha-Brook rearrangement is …

A novel reaction system for intramolecular addition of benzyl anions to alkynes was
developed by utilizing the [1, 2]-phospha-Brook rearrangement under Brønsted base …

A novel “umpolung” intramolecular cyclization of alkynyl imines, in which the electrophilic
imine sp2‐carbon formally serves as a nucleophilic site, was developed under Brønsted …

An approach involving the use of a bifunctional aminocatalyst containing Brønsted base and
iminium activation sites for asymmetric multicomponent reactions involving [1, 2]-phospha …

A synthetic method of tertiary alcohols was developed based on the formal umpolung
addition of aryl ketones with electrophiles utilizing the [1, 2]‐phospha‐Brook rearrangement …