Proton‐Coupled Electron Transfer in Photoredox Catalytic Reactions

N Hoffmann - European Journal of Organic Chemistry, 2017 - Wiley Online Library
Proton‐coupled electron transfer (PCET) is studied in different research domains of
chemistry. Many reports involve biochemical processes. Although related phenomena have …

TiO2 Photocatalysis for Transfer Hydrogenation

D Ma, S Zhai, Y Wang, A Liu, C Chen - Molecules, 2019 - mdpi.com
Catalytic transfer hydrogenation reactions, based on hydrogen sources other than gaseous
H2, are important processes that are preferential in both laboratories and factories …

Photocatalytic Pinacol C–C Coupling and Jet Fuel Precursor Production on ZnIn2S4 Nanosheets

G Han, X Liu, Z Cao, Y Sun - Acs Catalysis, 2020 - ACS Publications
Visible light-driven C–C bond formation has attracted increasing attention recently, thanks to
the advance in molecular photosensitizers and organometallic catalysts. Nevertheless …

Catalytic access to succinimide products containing stereogenic quaternary carbons

A Sadiq, TC Nugent - ChemistrySelect, 2020 - Wiley Online Library
Enantioselective α‐branched aldehyde Michael addition to N‐phenylmaleimide resulting in
non‐stereogenic quaternary carbon containing succinimides is common. Here we …

Photocatalysis with TiO2 applied to organic synthesis

N Hoffmann - Australian Journal of Chemistry, 2015 - CSIRO Publishing
Titanium dioxide is a versatile heterogeneous catalyst. Absorption of light by a TiO2 particle
leads to the formation of an electron–hole pair. Electron transfer from or to the particle …

Heterogeneous photoredox catalysis: reactions, materials, and reaction engineering

JZ Bloh, R Marschall - European Journal of Organic Chemistry, 2017 - Wiley Online Library
This microreview briefly summarizes recent developments in heterogeneous photoredox
catalysis, with a special focus on materials, reactors, and reaction design to optimize yields …

Selective Photocatalytic Reduction of 3‐Nitrophenol to 3‐Aminophenol by Anatase and Rutile TiO2 – What Stands Behind the Photoactivity?

K Yaemsunthorn, W Adamowicz, M Kobielusz… - …, 2023 - Wiley Online Library
The photocatalytic selective reduction of 3‐nitrophenol to 3‐aminophenol was studied in the
presence of titanium dioxide in the form of various anatase and rutile compositions. The …

[HTML][HTML] Preparative semiconductor photoredox catalysis: An emerging theme in organic synthesis

DW Manley, JC Walton - Beilstein journal of organic chemistry, 2015 - beilstein-journals.org
Heterogeneous semiconductor photoredox catalysis (SCPC), particularly with TiO 2, is
evolving to provide radically new synthetic applications. In this review we describe how …

Synthetic Approaches for CN Bonds by TiO2 Photocatalysis

D Ma, S Zhai, Y Wang, A Liu, C Chen - Frontiers in chemistry, 2019 - frontiersin.org
Nitrogen-containing organic compounds possess the most important status in drug
molecules and agricultural chemicals. More than 80% currently used drugs have at least a …

Reversal of reaction type selectivity by Lewis acid coordination: the ortho photocycloaddition of 1-and 2-naphthaldehyde

S Stegbauer, N Jeremias, C Jandl, T Bach - Chemical Science, 2019 - pubs.rsc.org
The value of a specific substrate class for synthetic applications is greatly enhanced if
different types of reactions can be performed selectively upon a judicious choice of reaction …