Layered oxide cathodes for sodium-ion batteries: storage mechanism, electrochemistry, and techno-economics

W Zuo, A Innocenti, M Zarrabeitia… - Accounts of Chemical …, 2023 - ACS Publications
Conspectus Lithium-ion batteries (LIBs) are ubiquitous in all modern portable electronic
devices such as mobile phones and laptops as well as for powering hybrid electric vehicles …

Challenges and prospects of sodium‐ion and potassium‐ion batteries for mass production

K Sada, J Darga, A Manthiram - Advanced Energy Materials, 2023 - Wiley Online Library
The exponential growth of the lithium‐ion (LIB) market is causing a significant disparity
between the supply chain and demand for its resources. In this regard, sodium‐ion and …

High-entropy Na-deficient layered oxides for sodium-ion batteries

H Wang, X Gao, S Zhang, Y Mei, L Ni, J Gao, H Liu… - ACS …, 2023 - ACS Publications
Sodium layered oxides always suffer from sluggish kinetics and deleterious phase
transformations at deep-desodiation state (ie.,> 4.0 V) in O3 structure, incurring inferior rate …

Niobium-doped layered cathode material for high-power and low-temperature sodium-ion batteries

Q Shi, R Qi, X Feng, J Wang, Y Li, Z Yao… - Nature …, 2022 - nature.com
The application of sodium-based batteries in grid-scale energy storage requires electrode
materials that facilitate fast and stable charge storage at various temperatures. However, this …

Recent progress in the emerging modification strategies for layered oxide cathodes toward practicable sodium ion batteries

B Peng, G Wan, N Ahmad, L Yu, X Ma… - Advanced Energy …, 2023 - Wiley Online Library
Low‐cost sodium‐ion batteries (SIBs) have been extensively considered as a supplement or
even a replacement for successful lithium‐ion batteries. However, the practical application of …

Homeostatic solid solution in layered transition-metal oxide cathodes of sodium-ion batteries

M Ren, S Zhao, S Gao, T Zhang, M Hou… - Journal of the …, 2022 - ACS Publications
Two-phase transformation reaction is ubiquitous in solid-state electrochemistry; however, it
usually involves inferior structure rearrangement upon extraction and insertion of large-sized …

Advanced cobalt-free cathode materials for sodium-ion batteries

S Chu, S Guo, H Zhou - Chemical Society Reviews, 2021 - pubs.rsc.org
Attempts to utilize lithium-ion batteries (LIBs) in large-scale electrochemical energy storage
systems have achieved initial success, and solid-state LIBs using metallic lithium as the …

W‐Doping Induced Efficient Tunnel‐to‐Layered Structure Transformation of Na0.44Mn1‐xWxO2: Phase Evolution, Sodium‐Storage Properties, and Moisture …

Q Ding, W Zheng, A Zhao, Y Zhao… - Advanced Energy …, 2023 - Wiley Online Library
Abstract Na0. 44MnO2 is a promising cathode material for sodium‐ion batteries owing to its
excellent cycling stability and low cost. However, insufficient sodium storage sites still hinder …

Boosting the reversibility and kinetics of anionic redox chemistry in sodium-ion oxide cathodes via reductive coupling mechanism

Y Wang, X Zhao, J Jin, Q Shen, Y Hu… - Journal of the …, 2023 - ACS Publications
Activating anionic redox chemistry in layered oxide cathodes is a paradigmatic approach to
devise high-energy sodium-ion batteries. Unfortunately, excessive oxygen redox usually …

Annealing in argon universally upgrades the Na‐storage performance of Mn‐based layered oxide cathodes by creating bulk oxygen vacancies

J Jin, Y Liu, X Zhao, H Liu, S Deng, Q Shen… - Angewandte …, 2023 - Wiley Online Library
Manganese‐rich layered oxide cathodes of sodium‐ion batteries (SIBs) are extremely
promising for large‐scale energy storage owing to their high capacities and cost …