Photoprotection: extending lessons learned from studying natural sunscreens to the design of artificial sunscreen constituents
Evolution has ensured that plants and animals have developed effective protection
mechanisms against the potentially harmful effects of incident ultraviolet radiation (UVR) …
mechanisms against the potentially harmful effects of incident ultraviolet radiation (UVR) …
The role of πσ* states in the photochemistry of heteroaromatic biomolecules and their subunits: insights from gas-phase femtosecond spectroscopy
GM Roberts, VG Stavros - Chemical Science, 2014 - pubs.rsc.org
In an effort to illuminate why nature has chosen a particular set of bio-molecular 'building-
blocks' for life, recent years have seen an up-surge of gas-phase spectroscopy experiments …
blocks' for life, recent years have seen an up-surge of gas-phase spectroscopy experiments …
Structure and dynamic role of conical intersections in the πσ*-mediated photodissociation reactions
Conical intersection as a dynamic funnel in nonadiabatic transition dictates many important
chemical reaction outputs such as reaction rates, yields, and energy disposals especially for …
chemical reaction outputs such as reaction rates, yields, and energy disposals especially for …
Ab Initio Study of Potential Ultrafast Internal Conversion Routes in Oxybenzone, Caffeic Acid, and Ferulic Acid: Implications for Sunscreens
Oxybenzone (OB) and ferulic acid (FA) both find use in commercial sunscreens; caffeic acid
(CA) differs from FA by virtue of an− OH group in place of a− OCH3 group on the aromatic …
(CA) differs from FA by virtue of an− OH group in place of a− OCH3 group on the aromatic …
Expanding the range of hierarchical equations of motion by tensor-train implementation
R Borrelli, S Dolgov - The Journal of Physical Chemistry B, 2021 - ACS Publications
The non-equilibrium thermo-field dynamics formulation of the hierarchical equations of
motion combined with the tensor-train representation of the density matrix is discussed, and …
motion combined with the tensor-train representation of the density matrix is discussed, and …
Theoretical insights into the photo-protective mechanisms of natural biological sunscreens: building blocks of eumelanin and pheomelanin
B Marchetti, TNV Karsili - Physical Chemistry Chemical Physics, 2016 - pubs.rsc.org
Eumelanin (EM) and pheomelanin (PM) are ubiquitous in mammalian skin and hair–
protecting against harmful radiation from the sun. Their primary roles are to absorb solar …
protecting against harmful radiation from the sun. Their primary roles are to absorb solar …
Ultraviolet spectroscopy of fundamental lignin subunits: Guaiacol, 4-methylguaiacol, syringol, and 4-methylsyringol
JC Dean, P Navotnaya, AP Parobek… - The Journal of …, 2013 - pubs.aip.org
Ultraviolet spectroscopy of the G-and S-type lignin subunits, guaiacol (G) and syringol (S),
along with their para-methylated derivatives 4-methylguaiacol (4-MG) and 4-methylsyringol …
along with their para-methylated derivatives 4-methylguaiacol (4-MG) and 4-methylsyringol …
Intermolecular hydrogen bonding modulates O‐H photodissociation in molecular aggregates of a catechol derivative
The catechol functional group plays a major role in the chemistry of a wide variety of
molecules important in biology and technology. In eumelanin, intermolecular hydrogen …
molecules important in biology and technology. In eumelanin, intermolecular hydrogen …
Solvent induced conformer specific photochemistry of guaiacol
SE Greenough, MD Horbury, JOF Thompson… - Physical Chemistry …, 2014 - pubs.rsc.org
Using a combination of ultrafast solution-and gas-phase spectroscopies, together with high-
level theory calculations, we demonstrate that we are able to track conformer-specific …
level theory calculations, we demonstrate that we are able to track conformer-specific …
Photofragmentation spectroscopy of cold protonated aromatic amines in the gas phase
G Féraud, M Broquier, C Dedonder-Lardeux… - Physical Chemistry …, 2014 - pubs.rsc.org
The electronic spectra of cold protonated aromatic amines: anilineH+ C6H5–NH3+,
benzylamineH+ C6H5–CH2–NH3+ and phenylethylamineH+ C6H5–(CH2) 2–NH3+ have …
benzylamineH+ C6H5–CH2–NH3+ and phenylethylamineH+ C6H5–(CH2) 2–NH3+ have …