Multiblock polymers: Panacea or Pandora's box?

FS Bates, MA Hillmyer, TP Lodge, CM Bates… - Science, 2012 - science.org
Advances in synthetic polymer chemistry have unleashed seemingly unlimited strategies for
producing block polymers with arbitrary numbers (n) and types (k) of unique sequences of …

Recent developments in fully fluctuating field-theoretic simulations of polymer melts and solutions

KT Delaney, GH Fredrickson - The Journal of Physical Chemistry …, 2016 - ACS Publications
We review the latest developments in computational methods for direct simulation of fully
fluctuating field theories of polymeric assemblies. In this context, we describe a newly …

Broadly accessible self-consistent field theory for block polymer materials discovery

A Arora, J Qin, DC Morse, KT Delaney… - …, 2016 - ACS Publications
Self-consistent field theory (SCFT) is a powerful tool for the design and interpretation of
experiments on block polymer materials. In this Perspective, we lower the barrier to entry to …

Hierarchical self-assembly of ABC-type bottlebrush copolymers

Q Song, Q Dong, R Liang, Y Xue, M Zhong… - Macromolecules, 2023 - ACS Publications
We have performed dissipative particle dynamics simulations to study the self-assembly of
ABC-type bottlebrush copolymers (BBCPs), one portion of whose backbone is grafted by …

Macromolecular metallurgy of binary mesocrystals via designed multiblock terpolymers

N Xie, M Liu, H Deng, W Li, F Qiu… - Journal of the American …, 2014 - ACS Publications
Self-assembling block copolymers provide access to the fabrication of various ordered
phases. In particular, the ordered spherical phases can be used to engineer soft …

Defects in the self-assembly of block copolymers and their relevance for directed self-assembly

W Li, M Müller - Annual review of chemical and biomolecular …, 2015 - annualreviews.org
Block copolymer self-assembly provides a platform for fabricating dense, ordered
nanostructures by encoding information in the chemical architecture of multicomponent …

Cornucopia of nanoscale ordered phases in sphere-forming tetrablock terpolymers

S Chanpuriya, K Kim, J Zhang, S Lee, A Arora… - ACS …, 2016 - ACS Publications
We report the phase behavior of a series of poly (styrene)-b-poly (isoprene)-b-poly
(styrene)′-b-poly (ethylene oxide)(SIS′ O) tetrablock terpolymers. This study was …

Complete photonic band gaps with nonfrustrated ABC bottlebrush block polymers

J Lequieu, T Quah, KT Delaney… - ACS macro …, 2020 - ACS Publications
Bottlebrush block polymers are a promising platform for self-assembled photonic materials,
yet most work has been limited to one-dimensional photonic crystals based on the lamellar …

Directed Self-Assembly of Diamond Networks in Triblock Terpolymer Films on Patterned Substrates

D Abdelrahman, R Iseli, M Musya, B Jinnai… - … applied materials & …, 2023 - ACS Publications
Block copolymers (BCPs) are particularly effective in creating soft nanostructured templates
for transferring complex 3D network structures into inorganic materials that are difficult to …

How does your gyroid grow? A mesoatomic perspective on supramolecular, soft matter network crystals

GM Grason, EL Thomas - Physical Review Materials, 2023 - APS
We propose and describe a framework to understand the structure of supramolecular
network crystals formed in soft matter in terms of mesoatomic building blocks, collective …