Pendant amines play an invaluable role in chemical reactivity, especially for molecular
catalysts based on earth-abundant metals. As inspired by [FeFe]-hydrogenases, which …

Molecular catalysis plays an essential role in both natural and artificial photosynthesis (AP).
However, the field of molecular catalysis for AP has gradually declined in recent years …

Proton activity at the electrified interface is central to the kinetics of proton-coupled electron
transfer (PCET) reactions for making chemicals and fuels. Here we employ a library of protic …

The synthesis of renewable fuels from abundant water or the greenhouse gas CO2 is a
major step toward creating sustainable and scalable energy storage technologies. In the last …

Carbon dioxide is one of the end products of combustion, and is not a benign component of
the atmosphere. The concentration of CO2 in the atmosphere has reached unprecedented …

Proton transfer is vital for many biological and chemical reactions. Hydrogen‐bonded water‐
containing networks are often found in enzymes to assist proton transfer, but similar strategy …

Efficient evolution of hydrogen through electrocatalysis at low overpotentials holds
tremendous promise for clean energy. Hydrogen evolution can be easily achieved by …

The pursuit of solar fuels has motivated extensive research on molecular electrocatalysts
capable of evolving hydrogen from protic solutions, reducing CO2, and oxidizing water …

This article reviews recent significant advances in the field of water splitting. Catalysts play
very important roles in two half reactions of water splitting-water reduction and water …

Reduction of acids to molecular hydrogen as a means of storing energy is catalyzed by
platinum, but its low abundance and high cost are problematic. Precisely controlled delivery …