Regioselective halogenation of arenes and heterocycles with N-halosuccinimides in
fluorinated alcohols is disclosed. Under mild condition reactions, a wide diversity of …

Chiral recognition is of importance not only in living systems but also in estimating the
optical purity of enantiomeric drugs and fabricating advanced materials. Herein we report a …

For about 300 solvents, we propose a database of new solvent parameters describing
empirically solute/solvent interactions: DI for dispersion and induction, ES for electrostatic …

A variety of physicochemical properties and several hydrogen-bond donors have been used
to define methods and to build scales aiming at measuring the hydrogen-bond acceptance …

An effective and clean FC alkylation of indoles and electron-rich arenes with β-nitroalkenes
in HFIP was reported. The desired products are formed rapidly in excellent yields under mild …

This book introduces the concepts, theory and experimental knowledge concerning solvent
effects on the rate and equilibrium of chemical reactions of all kinds. It begins with basic …

An effective, mild, and clean method for the C–H amination of free anilines with
azodicarboxylates in 1, 1, 1, 3, 3, 3‐hexafluoro‐2‐propanol (HFIP) without the need for any …

The unique combination of hexafluoroisopropanol (HFIP) employed as solvent and
hyperbaric conditions (10–15 kbar) allows unprecedented 1, 4-addition of poor …

Two imidazolium chloride ionic liquids (ILs) were mixed with urea for chitosan dissolution.
Ionic liquids were [Amim] Cl and [Etmim] Cl (1-allyl-3-methyl-imidazolium chloride and 3 …

Eutectic mixtures and deep eutectic solvents (DESs) are promising green media for the pre-
treatment of lignocellulose materials. They can be harnessed for the swelling of cellulose …