Processes to separate enantiomers

H Lorenz, A Seidel‐Morgenstern - … Chemie International Edition, 2014 - Wiley Online Library
The provision of pure enantiomers is of increasing importance not only for the
pharmaceutical industry but also for agrochemistry and biotechnology. In general, there are …

The diarylprolinol silyl ether system: a general organocatalyst

KL Jensen, G Dickmeiss, H Jiang… - Accounts of chemical …, 2012 - ACS Publications
The past few decades have witnessed some of the most important and revolutionizing
advances in the field of asymmetric catalysis. Chemists no longer rely solely on natural …

Binaphthyl scaffold: a class of versatile structure in asymmetric C–H functionalization

Q Yue, B Liu, G Liao, BF Shi - ACS Catalysis, 2022 - ACS Publications
Over the past decades, transition metal-catalyzed enantioselective C–H functionalization
has emerged as a straightforward and powerful tool for the rapid access to chiral molecules …

[图书][B] Asymmetric catalysis on industrial scale: challenges, approaches and solutions

HU Blaser, HJ Federsel - 2011 - books.google.com
This second edition of the pioneering work on this hot topic captures the major trends and
latest achievements in the art of asymmetric catalysis on an industrial scale. A number of …

Organocatalytic enantioselective desymmetrisation

A Borissov, TQ Davies, SR Ellis, TA Fleming… - Chemical Society …, 2016 - pubs.rsc.org
Organocatalytic enantioselective desymmetrisation of achiral or meso compounds is a
powerful strategy for the construction of enantiomerically enriched complex molecules, often …

A Simple Recipe for Sophisticated Cocktails: Organocatalytic One‐Pot Reactions—Concept, Nomenclature, and Future Perspectives

Ł Albrecht, H Jiang… - Angewandte Chemie …, 2011 - Wiley Online Library
Asymmetric organocatalysis has been successfully incorporated in many multistep one‐pot
sequences to provide simple access to structurally complex target molecules in a highly …

Rhodium-catalyzed asymmetric arylation

P Tian, HQ Dong, GQ Lin - ACS Catalysis, 2012 - ACS Publications
Rhodium-catalyzed asymmetric arylation (RCAA) reactions provide one of the most
straightforward and powerful ways to introduce aryl fragments in an enantioselective …

Pd (II)-catalyzed enantioselective C–H activation/C–O bond formation: synthesis of chiral benzofuranones

XF Cheng, Y Li, YM Su, F Yin, JY Wang… - Journal of the …, 2013 - ACS Publications
Pd (II)-catalyzed enantioselective C–H activation of phenylacetic acids followed by an
intramolecular C–O bond formation afforded chiral benzofuranones. This reaction provides …

Recent progress in asymmetric bifunctional catalysis using multimetallic systems

M Shibasaki, M Kanai, S Matsunaga… - Accounts of chemical …, 2009 - ACS Publications
The concept of bifunctional catalysis, wherein both partners of a bimolecular reaction are
simultaneously activated, is very powerful for designing efficient asymmetric catalysts …

Construction of N–C Axial Chirality through Atroposelective C–H Olefination of N-Arylindoles by Palladium/Amino Acid Cooperative Catalysis

J Zhang, Q Xu, J Wu, J Fan, M Xie - Organic letters, 2019 - ACS Publications
Direct construction of N–C axial chirality via Pd-catalyzed atroposelective C–H olefination of
N-arylindoles is reported. The crucial role of chiral amino acid as a cocatalyst in the regio …