Conspectus The catalytic, asymmetric synthesis of complex molecules has been a core
focus of our research program for some time because developments in the area can have an …

The use of two or more metal catalysts in a reaction is a powerful synthetic strategy to access
complex targets efficiently and selectively from simple starting materials. While capable of …

Polypyridine-ligated nickel complexes are widely used as privileged catalysts in a variety of
cross-coupling reactions. The rapid adoption of these complexes is tentatively attributed to …

Two-dimensional (2D) hybrid halide perovskites come as a family (B) 2 (A) n− 1Pb n X3 n+ 1
(B and A= cations; X= halide). These perovskites are promising semiconductors for solar …

In drug discovery, the proportion of aliphatic carbons (C (sp 3)) and the presence of chiral
carbons in organic molecules are positively correlated to their chance of clinical success …

N2 is fixed as NH3 industrially by the Haber–Bosch process under harsh conditions,
whereas biological nitrogen fixation is achieved under ambient conditions, which has …

The biaryl structural motif is a predominant feature in many pharmaceutically relevant and
biologically active compounds. As a result, for over a century1 organic chemists have sought …

The synthesis of transition metal–dinitrogen complexes and the stoichiometric
transformation of their coordinated dinitrogen into ammonia and hydrazine have been the …

A Ni-catalyzed reductive cross-coupling of styrenyl aziridines with aryl iodides is reported.
This reaction proceeds by a stereoconvergent mechanism and is thus amenable to …

Recent advances in catalytic nitrogen fixation using well-defined molecular transition metal–
dinitrogen complexes and their precursors as catalysts under ambient or mild reaction …