Removal of heavy metals by covalent organic frameworks (COFs): a review on its mechanism and adsorption properties

EA Gendy, J Ifthikar, J Ali, DT Oyekunle… - Journal of …, 2021 - Elsevier
Covalent organic frameworks (COFs) have demonstrated a great potential in the removal of
heavy metals due to its high adsorption capacity, large surface area, tunable porosity …

Recent investigations and progress in environmental remediation by using covalent organic framework-based adsorption method: A review

N Zhang, A Ishag, Y Li, H Wang, H Guo, P Mei… - Journal of Cleaner …, 2020 - Elsevier
Adsorption is considered to be the most effective method for removing environmental
pollutants. Covalent organic frameworks (COFs, state-of-art 2D or 3D crystalline porous …

Pyridinium salt-based covalent organic framework with well-defined nanochannels for efficient and selective capture of aqueous 99TcO4−

M Hao, Z Chen, H Yang, GIN Waterhouse, S Ma… - Science bulletin, 2022 - Elsevier
Ionic covalent organic framework (COF) materials with high specific surface areas and well-
defined pore structures are desired for many applications yet seldom reported. Herein, we …

Identifying the Recognition Site for Selective Trapping of 99TcO4 in a Hydrolytically Stable and Radiation Resistant Cationic Metal–Organic Framework

L Zhu, D Sheng, C Xu, X Dai, MA Silver… - Journal of the …, 2017 - ACS Publications
Effective and selective removal of 99TcO4–from aqueous solution is highly desirable for
both waste partitioning and contamination remediation purposes in the modern nuclear fuel …

99TcO4 remediation by a cationic polymeric network

J Li, X Dai, L Zhu, C Xu, D Zhang, MA Silver, P Li… - Nature …, 2018 - nature.com
Direct removal of 99TcO4− from the highly acidic solution of used nuclear fuel is highly
beneficial for the recovery of uranium and plutonium and more importantly aids in the …

Radiation controllable synthesis of robust covalent organic framework conjugates for efficient dynamic column extraction of 99TcO4−

Y Wang, M Xie, J Lan, L Yuan, J Yu, J Li, J Peng… - Chem, 2020 - cell.com
Anion-scavenging materials tailored for 99 TcO 4− trapping are urgently needed for both
nuclear-related environmental remediation and management of spent nuclear fuel. For the …

Cationic covalent organic nanosheets for rapid and selective capture of perrhenate: an analogue of radioactive pertechnetate from aqueous solution

HJ Da, CX Yang, XP Yan - Environmental science & technology, 2019 - ACS Publications
Capture of radioactive TcO4–from nuclear wastes is extremely desirable for waste disposal
and environmental restoration. Here, we report the synthesis of hydrolytically stable cationic …

Rational design of a cationic polymer network towards record high uptake of 99TcO4 in nuclear waste

J Li, L Chen, N Shen, R Xie, MV Sheridan… - Science China …, 2021 - Springer
Abstract 99Tc is a long-lived radionuclide present in large amounts as TcO4-anion in used
nuclear fuel. Its removal from the waste stream is highly desirable because of its interference …

Optimizing radionuclide sequestration in anion nanotraps with record pertechnetate sorption

Q Sun, L Zhu, B Aguila, PK Thallapally, C Xu… - Nature …, 2019 - nature.com
The elimination of specific contaminants from competitors poses a significant challenge.
Rather than relying on a single direct interaction, the cooperation of multiple functionalities is …

Exceptional perrhenate/pertechnetate uptake and subsequent immobilization by a low-dimensional cationic coordination polymer: overcoming the hofmeister bias …

L Zhu, C Xiao, X Dai, J Li, D Gui, D Sheng… - … & Technology Letters, 2017 - ACS Publications
We report one of the most efficient scavenger materials, a cationic crystalline coordination
polymer SBN for trapping ReO4–, a surrogate for 99TcO4–, as an anionic radioactive …