A molecular level understanding of dynamics in condensed media is one of the current
challenges to chemical physics. The challenge stems from the many-body nature of …

Decay patterns of atomic hydrogen trapped in argon and krypton matrices are followed by
electron paramagnetic resonance (EPR). Hydrogen atoms are generated by uv-photolysis of …

The spectroscopy of free radicals and of radical containing entrance-channel complexes
embedded in superfluid helium nanodroplets is reviewed. The collection of dopants inside …

The ability of carbon radicals to act as hydrogen bond acceptors has been evaluated using
ab initio theoretical methods. A hybrid Hartree‐Fock Density Functional Theory based …

Free radicals C60F and C70F were generated in solid argon by means of chemical reaction
of photogenerated fluorine atoms with isolated fullerene molecules C60 or C70. High …

The potential of using the translational mobility of hydrogen, oxygen and fluorine atoms in
the crystals and solid matrices of inert gases for initiating solid-phase cryochemical reactions …

High-resolution infrared laser spectroscopy is used to study the CH 3⋯ HF and CD 3⋯ HF
radical complexes, corresponding to the exit-channel complex in the F+ CH 4→ H F+ CH 3 …

Electron spin resonance (ESR) measurements were carried out to study the rotation of
methyl radicals (CH 3) in a solid argon matrix at 14–35 K temperatures. The radicals were …

Electron spin resonance (ESR) measurements were carried out to study the rotation of
methyl radicals (CH 3) in a solid krypton matrix at 17–31 K temperature range. The radicals …

Earlier studies have shown that pure quantum mechanical effects on the “light” methyl
radical at low temperature minimize the anisotropy of CW EPR spectra to a high resolution …