First-row d-block element-catalyzed carbon–boron bond formation and related processes
SK Bose, L Mao, L Kuehn, U Radius… - Chemical …, 2021 - ACS Publications
Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …
modern synthetic organic chemistry, often affording unprecedented reactivity. The …
Photoinduced borylation for the synthesis of organoboron compounds: focus review
YM Tian, XN Guo, H Braunschweig, U Radius… - Chemical …, 2021 - ACS Publications
Organoboron compounds have important synthetic value and can be applied in numerous
transformations. The development of practical and convenient ways to synthesize boronate …
transformations. The development of practical and convenient ways to synthesize boronate …
Methodologies and strategies for selective borylation of C–Het and C–C bonds
M Wang, Z Shi - Chemical Reviews, 2020 - ACS Publications
Organoborons have emerged as versatile building blocks in organic synthesis to achieve
molecular diversity and as carboxylic acid bioisosteres with broad applicability in drug …
molecular diversity and as carboxylic acid bioisosteres with broad applicability in drug …
Unveiling extreme photoreduction potentials of donor–acceptor cyanoarenes to access aryl radicals from aryl chlorides
Since the seminal work of Zhang in 2016, donor–acceptor cyanoarene-based fluorophores,
such as 1, 2, 3, 5-tetrakis (carbazol-9-yl)-4, 6-dicyanobenzene (4CzIPN), have been widely …
such as 1, 2, 3, 5-tetrakis (carbazol-9-yl)-4, 6-dicyanobenzene (4CzIPN), have been widely …
Photochemical and electrochemical strategies in C–F bond activation and functionalization
Z Wang, Y Sun, LY Shen, WC Yang… - Organic Chemistry …, 2022 - pubs.rsc.org
The activation and functionalization of C–F bonds under mild conditions can serve as an
important tool for organic syntheses including the modification of pharmaceuticals and …
important tool for organic syntheses including the modification of pharmaceuticals and …
Generation of non-stabilized alkyl radicals from thianthrenium salts for C–B and C–C bond formation
C Chen, ZJ Wang, H Lu, Y Zhao, Z Shi - Nature Communications, 2021 - nature.com
Sulfonium salts bearing a positively charged sulfur atom with three organic substituents
have intrigued chemists for more than a century for their unusual structures and high …
have intrigued chemists for more than a century for their unusual structures and high …
Transition-metal-free, site-selective C–F arylation of polyfluoroarenes via electrophotocatalysis
YJ Chen, WH Deng, JD Guo, RN Ci… - Journal of the …, 2022 - ACS Publications
Direct CAr–F arylation is effective and sustainable for synthesis of polyfluorobiaryls with
different degrees of fluorination, which are important motifs in medical and material …
different degrees of fluorination, which are important motifs in medical and material …
Visible‐Light‐Induced Selective Defluoroborylation of Polyfluoroarenes, gem‐Difluoroalkenes, and Trifluoromethylalkenes
Fluorinated organoboranes serve as versatile synthetic precursors for the preparation of
value‐added fluorinated organic compounds. Recent progress has been mainly focused on …
value‐added fluorinated organic compounds. Recent progress has been mainly focused on …
An easy-to-perform evaluation of steric properties of Lewis acids
L Zapf, M Riethmann, SA Föhrenbacher, M Finze… - Chemical …, 2023 - pubs.rsc.org
Steric and electronic effects play a very important role in chemistry, as these effects influence
the shape and reactivity of molecules. Herein, an easy-to-perform approach to assess and …
the shape and reactivity of molecules. Herein, an easy-to-perform approach to assess and …
Nickel‐Catalyzed Stereo‐ and Enantioselective Cross‐Coupling of gem‐Difluoroalkenes with Carbon Electrophiles by C−F Bond Activation
Z Zhu, L Lin, J Xiao, Z Shi - Angewandte Chemie International …, 2022 - Wiley Online Library
Stereo‐and enantioselective cross‐electrophile coupling involving C− F bond activation is
reported. Treatment of gem‐difluoroalkenes with racemic benzyl electrophiles in the …
reported. Treatment of gem‐difluoroalkenes with racemic benzyl electrophiles in the …