Metal alkynyl σ complexes: Synthesis and materials

NJ Long, CK Williams - Angewandte Chemie International …, 2003 - Wiley Online Library
Metal alkynyl complexes hold a fascination for synthetic chemists, structural chemists, and
materials scientists alike. Harnessing the unique overlap of metal and carbon orbitals is a …

Synthetic approaches toward molecular and polymeric carbon allotropes

F Diederich, Y Rubin - Angewandte Chemie International …, 1992 - Wiley Online Library
Life on earth is based on compounds that have carbon frames and backbones. Today,
chemists have added to the world of biomolecules and biopolymers approximately 107 …

[图书][B] Olefin metathesis and metathesis polymerization

KJ Ivin, JC Mol - 1997 - books.google.com
This book is a follow-up to Ivins Olefin Metathesis,(Academic Press, 1983). Bringing the
standard text in the field up to date, this Second Edition is a result of rapid growth in the field …

Decomposition of a key intermediate in ruthenium-catalyzed olefin metathesis reactions

SH Hong, MW Day, RH Grubbs - Journal of the American …, 2004 - ACS Publications
Dinuclear ruthenium complex, with a bridging carbide and a hydride ligand, and
methyltricyclohexylphosphonium chloride result from thermal decomposition of olefin …

Organometallic molecular wires and other nanoscale-sized devices: an approach using the organoiron (dppe) Cp* Fe building block

F Paul, C Lapinte - Coordination chemistry reviews, 1998 - Elsevier
In this paper, the potential that organometallic architectures consisting of two transition metal
centers linked by an organic unsaturated spacer present for the study and development of …

Electronic communication in heterobinuclear organometallic complexes through unsaturated hydrocarbon bridges

A Ceccon, S Santi, L Orian, A Bisello - Coordination chemistry reviews, 2004 - Elsevier
Much of the interest about the construction of model compounds suitable for investigating
the phenomena associated with the interaction of two or more metal centers, the so-called …

Elemental Carbon Chain Bridging Two Iron Centers: Syntheses and Spectroscopic Properties of [Cp*(dppe) Fe-C4-FeCp*(dppe)] n+. cntdot. n [PF6]-. X-ray Crystal …

N Le Narvor, L Toupet, C Lapinte - Journal of the American …, 1995 - ACS Publications
Reaction of [Fe (Cp*)(dppe) Cl][1, Cp*=^-CsMes, dppe=?/* 12-ethylenebis
(diphenylphosphine)] and NH4-PF6 in methanol with equiv of MegSiC—CH produced the …

Transition metal complexes containing all-carbon ligands

MI Bruce, PJ Low - Advances in Organometallic Chemistry, 2004 - books.google.com
While small carbon molecules have been found in locations as diverse as interstellar
molecular clouds, carbon stars, hydrocarbon flames and laserablated carbon, bulk …

Twists and turns: Studies of the complexes and properties of bimetallic complexes featuring phenylene ethynylene and related bridging ligands

PJ Low - Coordination Chemistry Reviews, 2013 - Elsevier
The concept of a molecular-based electronic technology has been evolving for over 50
years, and the development of molecular designs for such components over this period has …

Methods for the Synthesis of μ‐Hydrocarbon Transition Metal Complexes without Metal–Metal Bonds

W Beck, B Niemer, M Wieser - … Chemie International Edition in …, 1993 - Wiley Online Library
Transition metal complexes in which hydrocarbons serve as σ, σ‐, σ, π‐or π, π‐bound
bridging ligands are currently of great interest. This review presents efficient and directed …