Photons or electrons? A critical comparison of electrochemistry and photoredox catalysis for organic synthesis
NES Tay, D Lehnherr, T Rovis - Chemical reviews, 2021 - ACS Publications
Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …
Photoinduced organocatalyzed atom transfer radical polymerization (O-ATRP): precision polymer synthesis using organic photoredox catalysis
DA Corbin, GM Miyake - Chemical reviews, 2021 - ACS Publications
The development of photoinduced organocatalyzed atom transfer radical polymerization (O-
ATRP) has received considerable attention since its introduction in 2014. Expanding on …
ATRP) has received considerable attention since its introduction in 2014. Expanding on …
Rational design of photocatalysts for controlled polymerization: effect of structures on photocatalytic activities
Over the past decade, the use of photocatalysts (PCs) in controlled polymerization has
brought new opportunities in sophisticated macromolecular synthesis. However, the …
brought new opportunities in sophisticated macromolecular synthesis. However, the …
Precision polymer synthesis by controlled radical polymerization: Fusing the progress from polymer chemistry and reaction engineering
During the first 100 years of polymer science, controlled radical polymerization (also
recommended as reversible deactivation radical polymerization) is undoubtedly a …
recommended as reversible deactivation radical polymerization) is undoubtedly a …
Toward green atom transfer radical polymerization: current status and future challenges
Reversible‐deactivation radical polymerizations (RDRPs) have revolutionized synthetic
polymer chemistry. Nowadays, RDRPs facilitate design and preparation of materials with …
polymer chemistry. Nowadays, RDRPs facilitate design and preparation of materials with …
The advent and development of organophotoredox catalysis
T Bortolato, S Cuadros, G Simionato… - Chemical …, 2022 - pubs.rsc.org
In the last decade, photoredox catalysis has unlocked unprecedented reactivities in
synthetic organic chemistry. Seminal advancements in the field have involved the use of well …
synthetic organic chemistry. Seminal advancements in the field have involved the use of well …
Photoinduced controlled/living polymerizations
The application of photochemistry in polymer synthesis is of interest due to the unique
possibilities offered compared to thermochemistry, including topological and temporal …
possibilities offered compared to thermochemistry, including topological and temporal …
Externally controlled atom transfer radical polymerization
Spatial and temporal regulations of ATRP by external stimuli are presented. Various ATRP
techniques, eATRP, photoATRP, and mechanoATRP, are controlled by electrical current …
techniques, eATRP, photoATRP, and mechanoATRP, are controlled by electrical current …
Beyond C 3 N 4 π-conjugated metal-free polymeric semiconductors for photocatalytic chemical transformations
Photocatalysis with stable, efficient and inexpensive metal-free catalysts is one of the most
promising options for non-polluting energy production. This review article covers the state-of …
promising options for non-polluting energy production. This review article covers the state-of …
Visible-light-promoted C–S cross-coupling via intermolecular charge transfer
Disclosed is a mild, scalable, visible-light-promoted cross-coupling reaction between thiols
and aryl halides for the construction of C–S bonds in the absence of both transition metal …
and aryl halides for the construction of C–S bonds in the absence of both transition metal …