Why is ferrocene so exceptional?

D Astruc - European Journal of Inorganic Chemistry, 2017 - Wiley Online Library
The appearance of ferrocene in the middle of the 20th century has revolutionized
organometallic chemistry and is now providing applications in areas as varied and …

Organophosphorus compounds in organic electronics

MA Shameem, A Orthaber - Chemistry–A European Journal, 2016 - Wiley Online Library
This Minireview describes recent advances of organophosphorus compounds as opto‐
electronic materials in the field of organic electronics. The progress of (hetero‐) phospholes …

Electrostatic interactions within mixed-valent compounds

A Hildebrandt, D Miesel, H Lang - Coordination Chemistry Reviews, 2018 - Elsevier
The electrochemical properties of bi-and multi-metallic compounds are a convolution of
several factors, among which through-bond electron transfer and through-space electrostatic …

Unusually Strong Long‐Distance Metal–Metal Coupling in Bis (ferrocene)‐Containing BOPHY: An Introduction to Organometallic BOPHYs

HM Rhoda, K Chanawanno, AJ King… - … A European Journal, 2015 - Wiley Online Library
The first organometallic BOPHY (BOPHY= bis (difluoroboron)‐1, 2‐bis {(pyrrol‐2‐yl)
methylene} hydrazine) containing two ferrocene substituents was prepared through a …

Ni(II) 10-Phosphacorrole: A Porphyrin Analogue Containing Phosphorus at the Meso Position

H Omori, S Hiroto, Y Takeda, H Fliegl… - Journal of the …, 2019 - ACS Publications
Ni (II) 10-Phosphacorrole, a porphyrinoid containing phosphorus at the meso position, was
synthesized from a bis (α, α′-dibromodipyrrin) Ni (II) complex and a phosphine anion via …

Observation of the Strong Electronic Coupling in Near-Infrared-Absorbing Tetraferrocene aza-Dipyrromethene and aza-BODIPY with Direct Ferrocene− α-and …

YV Zatsikha, CD Holstrom, K Chanawanno… - Inorganic …, 2017 - ACS Publications
The 1, 3, 7, 9-tetraferrocenylazadipyrromethene (3) and the corresponding 1, 3, 5, 7-
tetraferrocene aza-BODIPY (4) were prepared via three and four synthetic steps …

Probing electronic communications in heterotrinuclear Fe–Ru–Fe molecular wires formed by ruthenium (II) tetraphenylporphyrin and isocyanoferrocene or 1, 1 …

VN Nemykin, SV Dudkin, M Fathi-Rasekh… - Inorganic …, 2015 - ACS Publications
Two new heterotrinuclear Fe–Ru–Fe complexes of ruthenium (II) tetraphenylporphyrin
axially coordinated with a pair of isocyanoferrocene ((FcNC) 2RuTPP, 1) or 1, 1 …

Catalytic hydrofunctionalization reactions of 1, 3-diynes

V Cadierno - Catalysts, 2022 - mdpi.com
Metal-catalyzed hydrofunctionalization reactions of alkynes, ie, the addition of Y–H units (Y=
heteroatom or carbon) across the carbon–carbon triple bond, have attracted enormous …

Transition-Metal Carbonyl Complexes of 2,5-Diferrocenyl-1-phenyl-1H-phosphole

D Miesel, A Hildebrandt, M Korb… - …, 2015 - ACS Publications
Pentacarbonyl (2, 5-diferrocenyl-1-phenyl-1 H-phosphole) metal complexes 3a–c (3a, M=
Cr; 3b, M= Mo; 3c, M= W) have successfully been synthesized by the reaction of 2, 5 …

Increasing steric demand through flexible bulk–primary phosphanes with 2, 6-bis (benzhydryl) phenyl backbones

J Bresien, JM Goicoechea, A Hinz, MT Scharnhölz… - Dalton …, 2019 - pubs.rsc.org
Sterically demanding primary phosphanes of the type RBhp-PH2 (Bhp= 2, 6-bis
(benzhydryl)-4-R-phenyl; R= Me, tBu) could be prepared in high yields by modification of …