First-row d-block element-catalyzed carbon–boron bond formation and related processes
SK Bose, L Mao, L Kuehn, U Radius… - Chemical …, 2021 - ACS Publications
Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …
modern synthetic organic chemistry, often affording unprecedented reactivity. The …
The Versatile Reaction Chemistry of an Alpha-Boryl Diazo Compound
Y Liu, R Puig de la Bellacasa, B Li… - Journal of the …, 2021 - ACS Publications
The first α-boryl diazo compound that is capable of engaging in classic synthetic organic
diazo reaction chemistry is described. The diazomethyl-1, 2-azaborine 1, which is a BN …
diazo reaction chemistry is described. The diazomethyl-1, 2-azaborine 1, which is a BN …
Organocatalytic trans Phosphinoboration of Internal Alkynes
We report the first trans phosphinoboration of internal alkynes. With an organophosphine
catalyst, alkynoate esters and the phosphinoboronate Ph2P‐Bpin are efficiently converted …
catalyst, alkynoate esters and the phosphinoboronate Ph2P‐Bpin are efficiently converted …
Small molecule activation based on novel heavier group 13/15 interelement compounds, λ3,λ3-phosphanylalumanes
T Yanagisawa, Y Mizuhata… - Bulletin of the Chemical …, 2024 - academic.oup.com
As a new entry of heteroatom–heteroatom bond species, λ3, λ3-phosphanylalumanes,
having unperturbed P–Al single-bond species, are expected to show high reactivity due to …
having unperturbed P–Al single-bond species, are expected to show high reactivity due to …
Monomeric Triphosphinoboranes: Intramolecular Lewis Acid–Base Interactions between Boron and Phosphorus Atoms
A Ordyszewska, N Szynkiewicz, J Chojnacki… - Inorganic …, 2022 - ACS Publications
Herein, we present the synthesis of the first fully characterized monomeric
triphosphinoboranes. The simple reaction of boron tribromide with 3 equiv of bulky lithium …
triphosphinoboranes. The simple reaction of boron tribromide with 3 equiv of bulky lithium …
Diphosphinoboranes as Intramolecular Frustrated Lewis Pairs: P–B–P Bond Systems for the Activation of Dihydrogen, Carbon Dioxide, and Phenyl Isocyanate
N Szynkiewicz, A Ordyszewska, J Chojnacki… - Inorganic …, 2021 - ACS Publications
Herein, we present the first example of the activation of small molecules by P–B–P bond
systems. The reactivity study involves reactions of two selected diphosphinoboranes,(t …
systems. The reactivity study involves reactions of two selected diphosphinoboranes,(t …
The phosphinoboration of acyl chlorides
MC Murphy, A Trofimova, JHW LaFortune… - Dalton …, 2020 - pubs.rsc.org
This investigation examines the reactivity of phosphinoboronate esters Ph2PBpin (pin= 1, 2-
O2C2Me4) and Ph2PBcat (cat= 1, 2-O2C6H4), as well as other phosphinoboron species …
O2C2Me4) and Ph2PBcat (cat= 1, 2-O2C6H4), as well as other phosphinoboron species …
Addition of a Phosphinoboronate Ester to Borole and Borafluorene
Thieme E-Journals - Synlett / Full Text DE EN Home Products Journals Books Book Series
Service Library Service Help Contact Portal SYNLETT Full-text search Full-text search Author …
Service Library Service Help Contact Portal SYNLETT Full-text search Full-text search Author …
A Novel Reactivity of Phosphanylalumane (> P− Al<): Reversible Addition of a Saturated Interelement Bond to Olefins
T Yanagisawa, Y Mizuhata… - Chemistry–A European …, 2021 - Wiley Online Library
The reversible addition of olefins to a phosphanylalumane, P− Al single‐bond species, was
investigated. The P− Al bond added to ethylene and relatively small terminal alkenes …
investigated. The P− Al bond added to ethylene and relatively small terminal alkenes …
Metal phosphinohydrazone complexes
YS Panova, AV Sheyanova, VV Sushev… - Russian Chemical …, 2020 - Springer
The reaction of benzophenone hydrazone with chlorodiphenylphosphine in the presence of
triethylamine affords the monophosphino derivative Ph 2 C= NN (H) PPh 2 (1). The lithiation …
triethylamine affords the monophosphino derivative Ph 2 C= NN (H) PPh 2 (1). The lithiation …