Conspectus Transition-metal-catalyzed reductive coupling of electrophiles has emerged as
a powerful tool for the construction of molecules. While major achievements have been …

Hypervalent iodine (III) compounds have found wide application in modern organic
chemistry as environmentally friendly reagents and catalysts. Hypervalent iodine reagents …

The formation of silicon–carbon bonds through the selective coupling of two strong
electrophilic bonds has been less developed. We report here silylation reactions that …

The cross‐electrophile coupling has become a powerful tool for C− C bond formation, but its
potential for forging the C− Si bond remains unexplored. Here we report a cross‐electrophile …

An efficient cross-electrophile couplings of aryl fluorosulfates with vinyl chlorosilanes by
using nickel as transition metal catalyst and manganese as reductant has been achieved …

Transition metal‐catalyzed bissilylation reactions of alkynes with disilane reagents have
become one of the most straightforward and efficient protocols to rapidly produce structurally …

This review aims to highlight the role of silicon in drug discovery. Silicon and carbon are
often regarded as being similar with silicon located directly beneath carbon in the same …

A Cu-catalyzed highly selective silylation and borylation of alkenylsulfonium salts under mild
conditions is reported. The reaction provides easy access to various alkenylsilanes and …

Herein, we report a one-pot synthesis of styrene derivatives via a novel B (C6F5) 3-
catalyzed E-selective isomerization of readily accessible allyl silanes and subsequent …

The stereodefined and highly substituted vinylsilanes are essential building blocks for
constructing complex organic molecules. Transition metal‐mediated silylmetalation of …