Low valent group 14 compounds exhibit diverse structures and reactivities. The employment
of diazaborolyl anions (NHB anions), isoelectronic analogues to N-heterocyclic carbenes …

Radicals are unique molecular systems for applications in electronic devices due to their
open-shell electronic structures. Radicals can function as good electrical conductors and …

An efficient photochemical radical sulfonyl cyclization of designed dienes to medium-sized
benzo [b] azocines and benzo [b] azonines was developed. This chemoselective method …

Developing open-shell singlet (OS) diradicals with high luminescent properties and
exceptional single-molecule magnetoluminescence (ML) performance is extremely …

Polyradicals, ie, multispin organic molecules, are playing important roles in radical-based
material applications for their spin–spin interaction. A dynamic covalently bonded multispin …

Molecular carbons (MCs) are molecular cutouts of carbon materials. Doping with
heteroatoms and constructing open‐shell structures are two powerful approaches to achieve …

Heterocyclic diradicaloids with atom‐precise control over open‐shell nature are promising
materials for organic electronics and spintronics. Herein, we disclose quinoidal π‐extension …

Due to their intrinsic high reactivity, isolation of heavier analogues of carbynes remains a
great challenge. Here, we report the synthesis and characterization of a neutral …

Systems that possess open-and closed-shell behavior attract significant attention from
researchers due to their inherent redox and charge transport properties. Herein, we report …

Understanding the origin of regio-and stereoselectivities of radical reactions remains a great
challenge in radical chemistry. To address this, we conducted density functional theory …