50th Anniversary Perspective: RAFT PolymerizationA User Guide

S Perrier - Macromolecules, 2017 - ACS Publications
This Perspective summarizes the features and limitations of reversible addition–
fragmentation chain transfer (RAFT) polymerization, highlighting its strengths and …

On the critical role of RAFT agent design in reversible addition-fragmentation chain transfer (RAFT) polymerization

M Destarac - Polymer reviews, 2011 - Taylor & Francis
There are a certain number of precautions a polymer chemist should take before
undertaking a reversible addition-fragmentation chain transfer (RAFT) polymerization with a …

Expanding the scope of RAFT polymerization: recent advances and new horizons

MR Hill, RN Carmean, BS Sumerlin - Macromolecules, 2015 - ACS Publications
Reversible deactivation radical polymerization (RDRP) has revolutionized modern polymer
chemistry over the past two decades, thus laying the groundwork for the synthesis of …

Living radical polymerization by the RAFT process–a third update

G Moad, E Rizzardo, SH Thang - Australian Journal of Chemistry, 2012 - CSIRO Publishing
This paper provides a third update to the review of reversible deactivation radical
polymerization (RDRP) achieved with thiocarbonylthio compounds (ZC (= S) SR) by a …

Phosphorus‐Containing Gradient (Block) Copolymers via RAFT Polymerization and Postpolymerization Modification

KJ Sykes, S Harrisson… - … Chemistry and Physics, 2016 - Wiley Online Library
Reversible addition‐fragmentation chain transfer (RAFT) copolymerization of styrene (St)
and 4‐(diphenylphosphino) styrene (DPPS) is explored to establish the statistical …

Manganese phosphinocarbodithioate for RAFT polymerisation with sunlight-induced chain end post-treatment

I Kulai, A Karpus, L Soroka, DA Valyaev… - Polymer …, 2019 - pubs.rsc.org
A new manganese RAFT agent of the formula Cp (CO) 2MnP (Ph) 2C (S) SCH (CH3) Ph
was synthesized in a good overall yield by a three-step reaction from cymantrene and …

RAFT polymerization with triphenylstannylcarbodithioates (Sn-RAFT)

I Kulai, O Brusylovets, Z Voitenko, S Harrisson… - ACS Macro …, 2015 - ACS Publications
A new range of tin-based reversible addition–fragmentation chain-transfer (RAFT) agents is
described and evaluated for the polymerization of acrylamides, methyl acrylate and styrene …

Phosphinoyl and thiophosphinoylcarbodithioates: synthesis, molecular structure, and application as new efficient mediators for raft polymerization

S Mazières, I Kulai, R Geagea… - … A European Journal, 2015 - Wiley Online Library
New phosphinoyl and thiophosphinoylcarbodithioates were synthesized in a one‐pot
reaction from the corresponding phosphinochalcogenides. Compounds of this new …

Electronic structure predictions of the properties of non-innocent P-ligands in group 6B transition metal complexes

EB Garner III, AJ Arduengo III, R Streubel… - Dalton …, 2014 - pubs.rsc.org
Neutral group 6B (Cr, Mo, W) pentacarbonyl complexes M (CO) 5-L possessing various P-
ligands such as phosphines, phosphaalkenes, and phospha-quinomethanes can form …

Alkyl Triarylstannanecarbodithioates: Synthesis, Crystal Structures, and Efficiency in RAFT Polymerization

I Kulai, N Saffon‐Merceron, Z Voitenko… - … A European Journal, 2017 - Wiley Online Library
Eight alkyl triarylstannanecarbodithioates were synthesized starting from the corresponding
triarylstannyl chlorides. They were fully characterized by IR and 1H, 13C, and 119Sn NMR …