Ultra-wideline solid-state NMR spectroscopy

RW Schurko - Accounts of chemical research, 2013 - ACS Publications
Although solid-state NMR (SSNMR) provides rich information about molecular structure and
dynamics, the small spin population differences between pairs of spin states that give rise to …

Organocuprates and diamagnetic copper complexes: structures and nmr spectroscopic structure elucidation in solution

RM Gschwind - Chemical reviews, 2008 - ACS Publications
A key role of copper is generally accepted in various scientific fields, for example, in organic
synthesis for the formation of CC bonds, in superconductors, and in biological oxygenation …

Polymorphic copper iodide clusters: insights into the mechanochromic luminescence properties

Q Benito, XF Le Goff, S Maron, A Fargues… - Journal of the …, 2014 - ACS Publications
An in-depth study of mechanochromic and thermochromic luminescent copper iodide
clusters exhibiting structural polymorphism is reported and gives new insights into the origin …

Geometry flexibility of copper iodide clusters: variability in luminescence thermochromism

Q Benito, XF Le Goff, G Nocton, A Fargues… - Inorganic …, 2015 - ACS Publications
An original copper (I) iodide cluster of novel geometry obtained by using a diphosphine
ligand is reported and is formulated [Cu6I6 (PPh2 (CH2) 3PPh2) 3](1). Interestingly, this sort …

Evaluation of ligands effect on the photophysical properties of copper iodide clusters

B Huitorel, H El Moll, R Utrera-Melero… - Inorganic …, 2018 - ACS Publications
Luminescent materials based on copper complexes are currently receiving increasing
attention because of their rich photophysical properties, opening a wide field of applications …

New methods for the acquisition of ultra-wideline solid-state NMR spectra of spin-1/2 nuclides

AW MacGregor, LA O'Dell, RW Schurko - Journal of Magnetic Resonance, 2011 - Elsevier
The Wideband Uniform Rate Smooth Truncation–Carr–Purcell Meiboom–Gill (WURST–
CPMG) pulse sequence was recently introduced as a new method of acquiring ultra …

[Cu@Sn9]3− and [Cu@Pb9]3−: Intermetalloid Clusters with Endohedral Cu Atoms in Spherical Environments

S Scharfe, TF Fässler, S Stegmaier… - … A European Journal, 2008 - Wiley Online Library
Since the notification of the resemblance between homoatomic Zintl anions and the class of
fullerenes,[1] the discovery of several new polyhedra as well as endohedrally filled cages of …

Polymorphic Copper Iodide Anions: Luminescence Thermochromism and Mechanochromism of (PPh4)2[Cu2I4]

Y Thefioux, M Cordier, F Massuyeau… - Inorganic …, 2020 - ACS Publications
The photoluminescent stimuli-responsive properties of two crystalline polymorphs with the
formula (PPh4) 2 [Cu2I4] are reported. Distinct luminescence properties are exhibited by …

Combining theory and experiment to get insight into the amorphous phase of luminescent mechanochromic copper iodide clusters

R Utrera-Melero, B Huitorel, M Cordier… - Inorganic …, 2020 - ACS Publications
In the field of stimuli-responsive luminescent materials, mechanochromic compounds
exhibiting reversible emission color changes activated by mechanical stimulation present …

Application of Solid-State 35Cl NMR to the Structural Characterization of Hydrochloride Pharmaceuticals and their Polymorphs

H Hamaed, JM Pawlowski, BFT Cooper… - Journal of the …, 2008 - ACS Publications
Solid-state 35Cl NMR (SSNMR) spectroscopy is shown to be a useful probe of structure and
polymorphism in HCl pharmaceuticals, which constitute ca. 50% of known pharmaceutical …