Catenanes, a distinctive category of mechanically interlocked molecules composed of
intertwined macrocycles, have undergone significant advancements since their initial stages …

The novel selenoviologen-based tetracationic cyclophanes (green boxes 3 and 5) with rigid
electron-deficient cavities are synthesized via SN2 reactions in two steps. The green boxes …

Radicals, with their unpaired electrons, exhibit unique chemical and physical properties that
have long intrigued chemists. Despite early skepticism about their stability, the discovery of …

Organic trisradicals featuring threefold symmetry have attracted significant interest because
of their unique magnetic properties associated with spin frustration. Herein, we describe the …

Although electroactive chiral covalent–organic frameworks (CCOFs) are considered an ideal
platform for chiral electroanalysis, they are rarely reported due to the difficult selection of …

In the field of supramolecular chemistry, cyclophanes with novel properties are highly sought
after since they can be tailored to fulfill specific tasks. In this article, we incorporate …

This study reports the serendipitous discovery of intermolecular anionic mixed‐valence (MV)
and π‐dimer species in ortho‐pentannulated BisAzaCoroneneDiimides (BACDs) during …

Organic amines are ubiquitous and essential in the dye, polymer, and pharmaceutical
industries, but can also be highly corrosive and toxic. Developing a quick and efficient …

A p yr ro lodithiin-derived box-like cyclophane (ProBox), featuring an adaptive geometry with
stimuli-responsiveness, was designed and successfully constructed. The dynamic and …