Conformational analysis of furanoside-containing mono-and oligosaccharides

HA Taha, MR Richards, TL Lowary - Chemical Reviews, 2013 - ACS Publications
D-arabinofuranose (2), as well as many plants, which produce polysaccharides rich in L-
arabinofuranose (3) 11− 14 and D-fructofuranose (4). 6 Other examples include the …

Diving for accurate structures in the ocean of molecular systems with the help of spectroscopy and quantum chemistry

C Puzzarini, V Barone - Accounts of chemical research, 2018 - ACS Publications
Conspectus The prediction and interpretation of structural properties are the starting points
for a deep understanding of thermochemistry, kinetics, and spectroscopic signatures of …

Degradation mechanism and relative stability of methylammonium halide based perovskites analyzed on the basis of acid–base theory

EJ Juarez-Perez, LK Ono, I Uriarte… - … applied materials & …, 2019 - ACS Publications
The correct identification of all gases released during hybrid perovskite degradation is of
great significance to develop strategies to extend the lifespan of any device based on this …

Equilibrium and non-equilibrium furanose selection in the ribose isomerisation network

AV Dass, T Georgelin, F Westall, F Foucher… - Nature …, 2021 - nature.com
The exclusive presence of β-D-ribofuranose in nucleic acids is still a conundrum in prebiotic
chemistry, given that pyranose species are substantially more stable at equilibrium …

The conformational behaviour of free D-glucose—at last

JL Alonso, MA Lozoya, I Pena, JC López… - Chemical …, 2014 - pubs.rsc.org
The conformational behaviour of isolated D-glucose has been revealed in this work using
Fourier transform microwave spectroscopy coupled with laser ablation of crystalline α-and β …

Femtisecond single-mole infrared spectroscopy of molecular clusters

MA Suhm, F Kollipost - Physical Chemistry Chemical Physics, 2013 - pubs.rsc.org
The sensitivity limitations of Fourier transform infrared (FTIR) spectroscopy for the detection
of molecular clusters formed in rarefied gas expansions can be overcome by synchronizing …

Flexibility unleashed in acyclic monoterpenes: conformational space of citronellal revealed by broadband rotational spectroscopy

SR Domingos, C Pérez, C Medcraft… - Physical Chemistry …, 2016 - pubs.rsc.org
Conformational flexibility is intrinsically related to the functionality of biomolecules.
Elucidation of the potential energy surface is thus a necessary step towards understanding …

Toward the RNA-world in the interstellar medium—Detection of urea and search of 2-amino-oxazole and simple sugars

I Jiménez-Serra, J Martín-Pintado, VM Rivilla… - Astrobiology, 2020 - liebertpub.com
In the past decade, astrochemistry has witnessed an impressive increase in the number of
detections of complex organic molecules. Some of these species are of prebiotic interest …

Free fructose is conformationally locked

EJ Cocinero, A Lesarri, P Écija, A Cimas… - Journal of the …, 2013 - ACS Publications
Fructose has been examined under isolation conditions using a combination of UV ultrafast
laser vaporization and Fourier-transform microwave (FT-MW) spectroscopy. The rotational …

A first-principles exploration of the conformational space of sodiated pyranose assisted by neural network potentials

HT Phan, PK Tsou, PJ Hsu, JL Kuo - Physical Chemistry Chemical …, 2023 - pubs.rsc.org
Sampling the conformational space of monosaccharides using the first-principles methods is
important and as a database of local minima provides a solid base for interpreting …