Thiol–ene click chemistry

CE Hoyle, CN Bowman - Angewandte Chemie International …, 2010 - Wiley Online Library
Following Sharpless′ visionary characterization of several idealized reactions as click
reactions, the materials science and synthetic chemistry communities have pursued …

Thiol–ene chemistry for polymer coatings and surface modification–building in sustainability and performance

C Resetco, B Hendriks, N Badi, F Du Prez - Materials Horizons, 2017 - pubs.rsc.org
Future advancement of coatings relies on new synthetic building blocks and methods that
enable added functionality, while minimising the environmental impact and cost. This review …

Review of autoxidation and driers

MD Soucek, T Khattab, J Wu - Progress in Organic Coatings, 2012 - Elsevier
This article is an overview of the chemistry and driers used in autoxidatively cured coatings
and in particular alkyds. The drying process for alkyds and other unsaturated fatty acid …

Thiol‐En‐Klickchemie

CE Hoyle, CN Bowman - Angewandte Chemie, 2010 - Wiley Online Library
Nach Sharpless' visionärer Charakterisierung verschiedener idealisierter Reaktionen als
Klick‐Reaktionen hat man innerhalb der Materialwissenschaften und Synthesechemie …

Sequential curing of off-stoichiometric thiol–epoxy thermosets with a custom-tailored structure

X Fernández-Francos, AO Konuray, A Belmonte… - Polymer …, 2016 - pubs.rsc.org
A new dual-curing system based on sequential thiol–epoxy click polycondensation and
epoxy anionic homopolymerization was studied. Formulations of diglycidyl ether of …

Synthesis, thiol− yne “click” photopolymerization, and physical properties of networks derived from novel multifunctional alkynes

JW Chan, J Shin, CE Hoyle, CN Bowman… - …, 2010 - ACS Publications
Multifunctional alkynes (2, 3, or 4 ynes per monomer) were prepared utilizing the
nucleophile-catalyzed thio− Michael addition reaction from commercially available …

Photopolymerization of thiol-alkynes: polysulfide networks

JW Chan, H Zhou, CE Hoyle, AB Lowe - Chemistry of Materials, 2009 - ACS Publications
A series of photoinitiated reactions involving radical chain addition of dithiols across the
triple bonds of dialkynes results in quantitative loss of all of the thiol and alkyne groups in 1 …

Photochemical production of interpenetrating polymer networks; simultaneous initiation of radical and cationic polymerization reactions

JP Fouassier, J Lalevée - Polymers, 2014 - mdpi.com
In this paper, we propose to review the ways to produce, through photopolymerization,
interpenetrating polymer networks (IPN) based, eg, on acrylate/epoxide or …

Click-based dual-curing thermosets and their applications

X Ramis, X Fernández-Francos, S De la Flor… - Thermosets, 2018 - Elsevier
Dual curing is the methodology for obtaining thermosets by combining two different and
compatible polymerization reactions, taking place sequentially or simultaneously …

The use of click-type reactions in the preparation of thermosets

O Konuray, X Fernández-Francos, S De la Flor… - Polymers, 2020 - mdpi.com
Click chemistry has emerged as an effective polymerization method to obtain thermosets
with enhanced properties for advanced applications. In this article, commonly used click …