Much attention has been paid to imidoyl radical-involved reactions in recent years. As a
divergent reactive intermediate, imidoyl radicals are used for the synthesis of functionalized …

The re-discovery of arenediazonium salts as stable and easily accessible electrophiles for
radical aromatic substitutions initiated by single-electron transfer has led to the development …

Palladium‐catalyzed intramolecular carbopalladation of N‐aryl acrylamides followed by
migratory insertion of an isocyanide‐coordinated C (sp3)− Pd intermediate afforded an …

An electrochemical three-component reaction cascade Mumm rearrangement was
developed for the synthesis of imides. Commercially available aryl acids, nitriles, and …

A transition-metal-free method for the synthesis of C6 phenanthridine derivatives by arylative
cyclization of 2-isocyanobiphenyls with arylamines in one pot was developed. Mechanistic …

The number of research papers that report photocatalyst-free protocols is currently
increasing. Among the different approaches proposed, the conversion of a strong C–X bond …

An unprecedented catalyst-dependent regioselective [3+ 2] cycloaddition of isocyanides
with aryl diazonium salts is reported. 1, 3-Disubstituted 1, 2, 4-triazoles were selectively …

A mild and efficient visible-light-mediated diarylation of N-arylacrylamides with aryl
diazonium salts under mild conditions has been developed. This method provides …

A simple, straightforward, and highly efficient multicomponent one‐pot synthesis of
pharmaceutically interesting diverse functionalized O‐and N‐heterocyclic scaffolds, such as …

The photochemical metal‐free carboamidation of aryl radicals has been exploited for the
preparation of aromatic amides, including hetero‐and polyaromatic derivatives, under …