The Phenomenon of Self-Induced Diastereomeric Anisochrony and Its Implications in NMR Spectroscopy

F Aiello, G Uccello Barretta, F Balzano, F Spiaggia - Molecules, 2023 - mdpi.com
Nuclear magnetic resonance (NMR) spectroscopy is an analytical technique largely applied
in the analysis of discrimination processes involving enantiomeric substrates and chiral …

Chiral self-recognition in a bispericyclic cyclodimerisation reaction of 1-azadienes

A López-Francés, X del Corte… - Organic Chemistry …, 2023 - pubs.rsc.org
Hermaphroditism of molecules: as in nature some species behave as male or female
depending on the environment, herein we report a bispericyclic dimerisation of cyclic 1 …

Pronounced Self‐Induced Diastereomeric Anisochronism in Anisidine Amino Acid Diamides

JM Menke, O Trapp - Chemistry–A European Journal, 2024 - Wiley Online Library
The emergent properties resulting from selective supramolecular interactions are of
significant importance for materials and chemical systems. For the directed use of such …

Unraveling the Source of Self‐Induced Diastereomeric Anisochronism in Chiral Dipeptides

F Spiaggia, F Aiello, L Sementa… - … A European Journal, 2024 - Wiley Online Library
Mastering of analytical methods for accurate quantitative determinations of enantiomeric
excess is a crucial aspect in asymmetric catalysis, chiral synthesis, and pharmaceutical …

[HTML][HTML] Altering the mobile phase composition to enhance self-disproportionation of enantiomers in achiral chromatography

P Mruc, M Olbrycht, M Korbetskyy, D Antos - Journal of Chromatography A, 2024 - Elsevier
The influence of mobile phase composition on the efficiency of enantiomer separation by
achiral chromatography (ACh) was investigated. The separation was induced by the …

Harnessing the Chirality of Phosphorus Compounds, from Catalysis to Application

V Dašková - 2023 - research.rug.nl
Many bioactive molecules and essential building blocks of biological systems are chiral and
contain phosphorus (P) in the oxidation state (V). Such compounds are ubiquitous in nature …

Enzyme-Mediated Cross-Benzoin Reaction of Highly Enolizable Aldehydes and Aryl Aldehydes for Acess to Chiral Phosphonates

H Li, L Yu, Z Zhu, D Wu, Y Ju, D Li, J Zhang, G Zhu… - 2024 - chemrxiv.org
Enzymatic catalysis has emerged as an attractive technology for organic synthesis but
remains in its infancy for constructing biologically-relevant chiral phosphonates. Here, we …

[PDF][PDF] New Chiral NHC Ligands for Enantioselective Gold (I) Catalysis

L Enders - 2024 - helda.helsinki.fi
The control of chirality in molecules is an integral part of synthetic organic chemistry and
remains a highly challenging task to this day. Placing a stereocenter into the molecular …

[PDF][PDF] 5.1 SIDA-Effekt

JM Menke, O Trapp - Adaptive Systeme zur Erkennung und zum Transfer …, 2023 - d-nb.info
With increasing demands on materials and systems, supramolecular properties have
become more important. For tailored development, a deeper understanding of mechanism …

Organocatalytic Hydrophosphonylation Towards Enantioenriched Self-Recognizing Ureidophosphonates

B List, S Brunen - Synfacts, 2023 - thieme-connect.com
Significance: Feringa and co-workers report a chiral phosphoric acid-catalyzed
hydrophosphonylation of alkylidene ureas to yield corresponding ureidophosphonates with …