The preparation, structure, dynamic behavior in solution, and reactivity of polyhydride
complexes of platinum group metals, described during the last three decades, are …

The application of density functional theory (DFT) methods in catalysis has been fast
growing in the last decades thanks to both the availability of more powerful high computing …

A detailed catalytic, stoichiometric, and mechanistic study on the dehydrocoupling of H3B·
NMe2H and dehydropolymerization of H3B· NMeH2 using the [Rh (Xantphos)]+ fragment is …

Ammonia–borane (AB) has been in the spotlight for its much touted potential as an onboard
vehicular hydrogen delivery material. Over the past decade, catalyzed dehydrogenation …

The readily available iron carbonyl complexes,[CpFe (CO) 2] 2 (1) and CpFe (CO) 2I (2)(Cp=
η-C5H5), were found to be efficient precatalysts for the dehydrocoupling/dehydrogenation of …

The multistage Rh-catalyzed dehydrocoupling of the secondary amine-borane H3B·
NMe2H, to give the cyclic amino-borane [H2BNMe2] 2, has been explored using catalysts …

Multiple metal-bound oligomers in the dehydropolymerisation of H3B· NH3 have been
observed by electrospray-ionisation mass spectrometry and NMR spectroscopy using the …

Dinuclear metal–metal cooperative effects are important in catalysis involving the activation
of small molecules with strong bonds. Here, we report density functional theory calculations …

Hydrogen storage is an indispensable component of hydrogen-based fuel economy.
Chemical hydrogen storage relies on the development of lightweight compounds which can …

Remote control: The title reaction is the first example of a catalyzed dehydrogenative
cyclization (CDC) of diamine–monoboranes to give cyclic diaminoboranes. The cyclization …