Multifunctional Cytochrome c: Learning New Tricks from an Old Dog

D Alvarez-Paggi, L Hannibal, MA Castro… - Chemical …, 2017 - ACS Publications
Cytochrome c (cyt c) is a small soluble heme protein characterized by a relatively flexible
structure, particularly in the ferric form, such that it is able to sample a broad conformational …

[HTML][HTML] Electrochemistry of surface-confined enzymes: Inspiration, insight and opportunity for sustainable biotechnology

LP Jenner, JN Butt - Current Opinion in Electrochemistry, 2018 - Elsevier
Highlights•New strategies for enzyme electrochemistry.•Recent applications of enzyme
electrochemistry.•Synergies of fundamental and applied enzyme electrochemistry.Redox …

Thermodynamics of metalloprotein electron transfer reactions

VT Taniguchi, N Sailasuta-Scott, FC Anson… - Pure and Applied …, 1980 - degruyter.com
Thin—layer spectroelectrochemical methods have been used to determine the formal
reduction potentials of several electron transfer metalloproteins in the temperature range 5 …

Semisynthetic and biomolecular hydrogen evolution catalysts

B Kandemir, S Chakraborty, Y Guo, KL Bren - Inorganic chemistry, 2016 - ACS Publications
There has been great interest in the development of stable, inexpensive, efficient catalysts
capable of reducing aqueous protons to hydrogen (H2), an alternative to fossil fuels. While …

The enthalpic and entropic terms of the reduction potential of metalloproteins: Determinants and interplay

G Di Rocco, G Battistuzzi, M Borsari… - Coordination Chemistry …, 2021 - Elsevier
Splitting the reduction potential of electron transport (ET) proteins and redox
metalloenzymes into the enthalpic and entropic contributions is an insightful practice to …

How to turn an electron transfer protein into a redox enzyme for biosensing

A Ranieri, M Borsari, S Casalini, G Di Rocco, M Sola… - Molecules, 2021 - mdpi.com
Cytochrome c is a small globular protein whose main physiological role is to shuttle
electrons within the mitochondrial electron transport chain. This protein has been widely …

Towards Bacterial Resistance via the Membrane Strategy: Enzymatic, Biophysical and Biomimetic Studies of the Lipid cis‐trans Isomerase of Pseudomonas …

M Mauger, I Makarchuk, Y Molter, A Sansone… - …, 2024 - Wiley Online Library
The lipid cis‐trans isomerase (Cti) is a periplasmic heme‐c enzyme found in several
bacteria including Pseudomonas aeruginosa, a pathogen known for causing nosocomial …

Determining Redox Potentials of the Iron–Sulfur Clusters of the AdoMet Radical Enzyme Superfamily

SJ Maiocco, LM Walker, SJ Elliott - Methods in Enzymology, 2018 - Elsevier
While protein film electrochemistry (PFE) has proven to be an effective tool in the
interrogation of redox cofactors and assessing the electrocatalytic activity of many different …

Effect of motional restriction on the unfolding properties of a cytochrome c featuring a His/Met–His/His ligation switch

A Ranieri, CA Bortolotti, G Battistuzzi, M Borsari… - Metallomics, 2014 - academic.oup.com
Abstract The K72A/K73H/K79A variant of cytochrome c undergoes a reversible change from
a His/Met to a His/His axial heme ligation upon urea-induced unfolding slightly below …

Methionine Ligand Lability of Homologous Monoheme Cytochromes c

BD Levin, KA Walsh, KK Sullivan, KL Bren… - Inorganic …, 2015 - ACS Publications
Direct electrochemical analysis of adsorbed bacterial monoheme cytochromes c has
revealed a phenomenological loss of the axial methionine when examined using pyrolytic …