Green synthesis of polymer materials via enzyme-initiated RAFT polymerization

S Kumar, R Gaddala, S Thomas, J Schumacher… - Polymer …, 2024 - pubs.rsc.org
Enzymes are well-known biocatalysts for natural metabolic reactions and synthetic organic
reactions. For many decades, enzymatic catalysis has been successfully implemented for …

A concise review on polymer brushes and its interaction with surfactants: An approach towards smart materials

MG Lokesh, AK Tiwari - Journal of Molecular Liquids, 2024 - Elsevier
Unique macromolecular structures known as polymer brushes are made of individual
polymer chains that are free at one end and attached to a solid surface at the other. Polymer …

Synthesis and applications of a Y‐inimer with two orthogonal controlled free radical polymerization initiators

R Chen, JD Smith, NN Osores… - Journal of Polymer …, 2023 - Wiley Online Library
We report the synthesis of a Y‐shaped inimer that contains two orthogonal initiators for
ATRP and NMP. The inimer is synthesized through a one‐pot multi‐component reaction that …

Polymer Brush Growth by Surface‐Initiated Ring‐Opening Polymerization from a Cross‐Linked Polymer Thin Film

M Betancourt‐Ponce, B Govindarajan… - Advanced Functional …, 2024 - Wiley Online Library
Modification of a surface with polymer brushes has emerged as an effective approach to
tune the properties of a substrate. Brushes grown from an inimer‐containing cross‐linkable …

Size-dependent electrostatic adsorption of polymer-grafted gold nanoparticles on polyelectrolyte brushes

YC Kim, S Hoang, KI Winey… - ACS Applied Materials & …, 2024 - ACS Publications
Designing a functional surface that selectively adsorbs nanoparticles based on their size
and shape is essential for developing an advanced adsorption-based, postsynthesis …

Porous Morphology of High Grafting Density Mixed Polyelectrolyte Brushes Grown from a Y-Inimer Coating

JD Smith, R Chen, NN Osores, P Gopalan - Langmuir, 2024 - ACS Publications
Mixed A/B polyelectrolyte (PE) brushes of opposite charges are grown from a Y-shaped
initiator-bearing coating to facilitate intimate mixing of the A and B polyelectrolytes in a 1: 1 …

Nanoengineering Spikey Surfaces: Investigation of Reversible Organizational Control of Surface-Tethered Polypeptide Brushes

Y Huang, H Kim, LA Padilla Salas, WR Zipfel, SM Hur… - Langmuir, 2024 - ACS Publications
Nature serves as an important source of inspiration for the innovation and development of
micro-and nanostructures for advanced functional surfaces and substrates. One example …

Long‐Lasting Antibacterial PDMS Surfaces Constructed from Photocuring of End‐Functionalized Polymers

B Li, C Pang, S Chen, L Hong - Macromolecular Rapid …, 2024 - Wiley Online Library
A challenge remains in the development of anti‐infectious coatings for the inert surfaces of
biomedical devices that are prone to bacterial colonization and biofilm formation. Here, a …