Photoactive copper complexes: properties and applications

J Beaudelot, S Oger, S Perusko, TA Phan… - Chemical …, 2022 - ACS Publications
Photocatalyzed and photosensitized chemical processes have seen growing interest
recently and have become among the most active areas of chemical research, notably due …

Two-coordinate thermally activated delayed fluorescence coinage metal complexes: Molecular design, photophysical characters, and device application

TY Li, SJ Zheng, PI Djurovich, ME Thompson - Chemical Reviews, 2024 - ACS Publications
Since the emergence of the first green light emission from a fluorescent thin-film organic light
emitting diode (OLED) in the mid-1980s, a global consumer market for OLED displays has …

Gold (I) Multi‐Resonance Thermally Activated Delayed Fluorescent Emitters for Highly Efficient Ultrapure‐Green Organic Light‐Emitting Diodes

S Cai, GSM Tong, L Du, GKM So, FF Hung… - Angewandte …, 2022 - Wiley Online Library
Acceleration of singlet‐triplet intersystem crossings (ISC) is instrumental in bolstering triplet
exciton harvesting of multi‐resonance thermally activated delayed fluorescent (MR‐TADF) …

π-Extended ligands in two-coordinate coinage metal complexes

CN Muniz, J Schaab, A Razgoniaev… - Journal of the …, 2022 - ACS Publications
Two-coordinate carbene-MI-amide (cMa, MI= Cu, Ag, Au) complexes have emerged as
highly efficient luminescent materials for use in a variety of photonic applications due to their …

Efficient Reverse Intersystem Crossing in Carbene‐Copper‐Amide TADF Emitters via an Intermediate Triplet State

JP Zobel, AM Wernbacher… - Angewandte Chemie …, 2023 - Wiley Online Library
The mechanism behind reverse intersystem crossing (rISC) in metal‐based TADF emitters is
still under debate. Thermal rISC necessitates small singlet/triplet energy gaps as realized in …

Stable Tetradentate Gold(III)‐TADF Emitters with Close to Unity Quantum Yield and Radiative Decay Rate Constant of up to 2 × 106 s−1: High‐Efficiency Green OLEDs with Operational …

D Zhou, GSM Tong, G Cheng, YK Tang… - Advanced …, 2022 - Wiley Online Library
High maximum external quantum efficiency (EQEmax), small efficiency roll‐offs, and long
operational lifetime at practical luminances are three crucial parameters for …

Copper (I) complexes with planar chirality realize efficient circularly polarized electroluminescence

A Ying, L Zhan, Y Tan, X Cao, C Yang, S Gong - Science China Chemistry, 2023 - Springer
Chiral organometallic emitters hold great promise in potential and practical applications of
circularly polarized organic light-emitting diodes (CP-OLEDs). However, developing …

A Rising Star: Luminescent Carbene‐Metal‐Amide Complexes

A Ying, S Gong - Chemistry–A European Journal, 2023 - Wiley Online Library
Coinage metal (gold, silver, and copper) complexes are attractive candidates to substitute
the widely studied noble metal complexes, such as, iridium (III) and platinum (II), as …

Luminescent Bimetallic Two-Coordinate Gold (I) Complexes Utilizing Janus Carbenes

J Ma, J Schaab, S Paul, SR Forrest… - Journal of the …, 2023 - ACS Publications
A series of bimetallic carbene-metal-amide (cMa) complexes have been prepared with
bridging biscarbene ligands to serve as a model for the design of luminescent materials with …

Two-coordinate coinage metal complexes as solar photosensitizers

CN Muniz, CA Archer, JS Applebaum… - Journal of the …, 2023 - ACS Publications
Generating sustainable fuel from sunlight plays an important role in meeting the energy
demands of the modern age. Herein, we report two-coordinate carbene-metal-amide (cMa …