Recognition in the domain of molecular chirality: from noncovalent interactions to separation of enantiomers

P Peluso, B Chankvetadze - Chemical Reviews, 2022 - ACS Publications
It is not a coincidence that both chirality and noncovalent interactions are ubiquitous in
nature and synthetic molecular systems. Noncovalent interactivity between chiral molecules …

Self-assembled inorganic chiral superstructures

J Lv, X Gao, B Han, Y Zhu, K Hou, Z Tang - Nature Reviews Chemistry, 2022 - nature.com
Controlled assembly of inorganic nanoparticles with different compositions, sizes and
shapes into higher-order structures of collective functionalities is a central pursued objective …

Tailoring the photoluminescence of atomically precise nanoclusters

X Kang, M Zhu - Chemical Society Reviews, 2019 - pubs.rsc.org
Due to their atomically precise structures and intriguing chemical/physical properties, metal
nanoclusters are an emerging class of modular nanomaterials. Photo-luminescence (PL) is …

Atomically precise photothermal nanomachines

J Chen, P Gu, G Ran, Y Zhang, M Li, B Chen, H Lu… - Nature Materials, 2024 - nature.com
Interfacing molecular machines to inorganic nanoparticles can, in principle, lead to hybrid
nanomachines with extended functions. Here we demonstrate a ligand engineering …

[HTML][HTML] Tailoring gold nanocluster properties for biomedical applications: From sensing to bioimaging and theranostics

SM Farkhani, P Dehghankelishadi, A Refaat… - Progress in Materials …, 2024 - Elsevier
Gold nanomaterials have emerged as versatile systems which hold a great promise for
several biomedical applications. Among them, gold nanoclusters (AuNCs)—ultra-small …

Molecular reactivity of thiolate-protected noble metal nanoclusters: synthesis, self-assembly, and applications

Q Yao, Z Wu, Z Liu, Y Lin, X Yuan, J Xie - Chemical Science, 2021 - pubs.rsc.org
Thiolate-protected noble metal (eg, Au and Ag) nanoclusters (NCs) are ultra-small particles
with a core size of less than 3 nm. Due to the strong quantum confinement effects and …

Stereospecific interactions between chiral inorganic nanomaterials and biological systems

X Zhao, SQ Zang, X Chen - Chemical Society Reviews, 2020 - pubs.rsc.org
Chirality is ubiquitous in nature and plays mysterious and essential roles in maintaining key
biological and physiological processes. As biological systems display high selectivity for …

Interactions of metal nanoclusters with light: fundamentals and applications

T Chen, H Lin, Y Cao, Q Yao, J Xie - Advanced Materials, 2022 - Wiley Online Library
The interactions of materials with light determine their applications in various fields. In the
past decade, ultrasmall metal nanoclusters (NCs) have emerged as a promising class of …

A review of state of the art in phosphine ligated gold clusters and application in catalysis

RH Adnan, JML Madridejos, AS Alotabi… - Advanced …, 2022 - Wiley Online Library
Atomically precise gold clusters are highly desirable due to their well‐defined structure
which allows the study of structure–property relationships. In addition, they have potential in …

Chirality and surface bonding correlation in atomically precise metal nanoclusters

Y Li, T Higaki, X Du, R Jin - Advanced Materials, 2020 - Wiley Online Library
Chirality is ubiquitous in nature and occurs at all length scales. The development of
applications for chiral nanostructures is rising rapidly. With the recent achievements of …