Conspectus The study of carbohydrates has emerged as a crucial research area in various
disciplines due to their pivotal roles in cellular processes. To facilitate in-depth exploration of …

Glycosyl radical functionalization is one of the central topics in synthetic carbohydrate
chemistry. Recent advances in metal‐catalyzed cross‐coupling chemistry and …

Stereoselective C‐glycosylation reactions are increasingly gaining attention in carbohydrate
chemistry because they enable glycosyl precursors, readily accessible as anomeric …

Carbohydrates play important roles in medicinal chemistry and biochemistry. However, their
synthesis relies on specially designed glycosyl donors, which are often unstable and require …

Stereochemically pure saccharides have indispensable roles in fields ranging from
medicinal chemistry to materials science and organic synthesis. However, the development …

Deoxy‐β‐C‐glycosides represent an important class of carbohydrates that are present in
many bioactive molecules. However, owing to the lack of substituents at the C2 position, the …

Glycosyl anomeric radical addition reactions have been well‐explored and proved efficient
for the C‐alkyl glycosides synthesis, but multicomponent Domino transformations for the …

Glycosyl donor activation emerged as an enabling technology for anomeric
functionalization, but aimed primarily at O-glycosylation. In contrast, we herein disclose …

A step‐economical and operationally simple nickel‐catalyzed cross‐electrophile coupling of
aryl phosphates with aryl bromides through C− O bond cleavage, which precluded the …

C-Glycosyl peptides possess excellent metabolic stability and therapeutic properties and
thus play critical roles in biological studies as well as drug discoveries. However, the limited …