Sulfur-containing compounds have attracted considerable interest due to their wide-ranging
applications in pharmaceuticals, agriculture, natural products, and organic materials. The …

Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …

Enantioenriched boronic esters are widely used multipurpose building blocks in organic
synthesis. Multicomponent processes that deliver these organoboron compounds using non …

New borylation methodologies have been reported recently, wherein diboron (4)
compounds apparently participate in free radical couplings via the homolytic cleavage of the …

Aryl sulfones and aryl sulfonamides are of great importance in organic synthesis and
medicinal chemistry. Although ortho‐C− H functionalization of aryl sulfonyl compounds has …

Organoboron compounds are versatile intermediate for a diverse range of synthetic
transformations. The development of methodologies for the synthesis of organoboron …

We report a combined experimental and mechanistic study on the Buchwald–Hartwig
amination and C–S/S–H metathesis of aryl sulfides by selective activation of C–S bonds …

Sulfenate anions (RSO-) represent the conjugate base of sulfenic acids (RSOH) and are
known predominately for their S-nucleophilicity. In the early stages of sulfenate research this …

Transition metal‐catalyzed borylation has emerged as a powerful and versatile strategy for
synthesizing organoboron compounds. These compounds have found widespread …

A Cu-catalysed borylation of aryl alkyl sulfones was developed for the high yield synthesis of
versatile arylboronic esters using a readily prepared NHC–Cu catalyst. In addition, the …