Molecular magnetism: from chemical design to spin control in molecules, materials and devices

E Coronado - Nature Reviews Materials, 2020 - nature.com
The field of molecular magnetism is rapidly evolving towards the use of magnetic molecules
and molecule-based magnetic materials in physics-driven and nanotechnology-driven …

Magnetic functionalities in MOFs: from the framework to the pore

GM Espallargas, E Coronado - Chemical Society Reviews, 2018 - pubs.rsc.org
In this review, we show the different approaches developed so far to prepare metal–organic
frameworks (MOFs) presenting electronic functionalities, with particular attention to magnetic …

The rise of 3-d single-ion magnets in molecular magnetism: towards materials from molecules?

JM Frost, KLM Harriman, M Murugesu - Chemical science, 2016 - pubs.rsc.org
Single-molecule magnets (SMMs) that contain one spin centre (so-called single-ion
magnets) theoretically represent the smallest possible unit for spin-based electronic devices …

Constraining the coordination geometries of lanthanide centers and magnetic building blocks in frameworks: a new strategy for molecular nanomagnets

K Liu, X Zhang, X Meng, W Shi, P Cheng… - Chemical Society …, 2016 - pubs.rsc.org
Single-molecule magnets (SMMs) and single-chain magnets (SCMs), also known as
molecular nanomagnets, are molecular species of nanoscale proportions with the potential …

Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆

J Ferrando-Soria, J Vallejo, M Castellano… - Coordination Chemistry …, 2017 - Elsevier
Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …

Ionic metal-organic frameworks (iMOFs): Design principles and applications

A Karmakar, AV Desai, SK Ghosh - Coordination Chemistry Reviews, 2016 - Elsevier
Metal-organic frameworks (MOFs) have commanded significant attention in recent years on
account of the applicability of these materials across several disciplines in material …

Determining key local vibrations in the relaxation of molecular spin qubits and single-molecule magnets

L Escalera-Moreno, N Suaud… - The journal of …, 2017 - ACS Publications
To design molecular spin qubits and nanomagnets operating at high temperatures, there is
an urgent need to understand the relationship between vibrations and spin relaxation …

Post-synthetic ion-exchange process in nanoporous metal–organic frameworks; an effective way for modulating their structures and properties

Y Noori, K Akhbari - RSC advances, 2017 - pubs.rsc.org
Over the last two decades, metal–organic frameworks (MOFs) have received great attention
and the number of compounds reported is still growing, which is mainly due to their amazing …

A porous array of clock qubits

JM Zadrozny, AT Gallagher, TD Harris… - Journal of the …, 2017 - ACS Publications
Realizing atomic-level spatial control over qubits, the fundamental units of both quantum
information processing systems and quantum sensors, constitutes a crucial cross-field …

Single-ion magnetism behaviors in lanthanide (III) based coordination frameworks

Q Wan, M Wakizaka, M Yamashita - Inorganic Chemistry Frontiers, 2023 - pubs.rsc.org
Single-ion magnets (SIMs) and single-molecule magnets (SMMs) are typically made up of
3d and/or 4f complexes that possess significant energy barriers to prevent the spin reversal …