Current developments in esterification reaction: A review on process and parameters

Z Khan, F Javed, Z Shamair, A Hafeez, T Fazal… - Journal of Industrial and …, 2021 - Elsevier
Esters are among the highest volume of industrial organic compounds produced. They are
frequently employed in various domestic and industrial processes. Fischer esterification …

Applied biocatalysis beyond just buffers–from aqueous to unconventional media. Options and guidelines

MMCH van Schie, JD Spöring, M Bocola… - Green …, 2021 - pubs.rsc.org
In nature, enzymes conventionally operate under aqueous conditions. Because of this,
aqueous buffers are often the choice for reaction media when enzymes are applied in …

Solvent-free esterifications mediated by immobilized lipases: A review from thermodynamic and kinetic perspectives

RR Sousa, ASA Silva, R Fernandez-Lafuente… - Catalysis Science & …, 2021 - pubs.rsc.org
Esters are a highly relevant class of compounds in the industrial context, and biocatalysis
applied to ester syntheses is already a reality for some chemical companies. Their …

Enzymatic synthesis of poly (glycerol sebacate): Kinetics, chain growth, and branching behavior

GB Perin, MI Felisberti - Macromolecules, 2020 - ACS Publications
Immobilized Candida antarctica lipase B (CALB)-catalyzed polycondensation of glycerol
and sebacic acid at mild reaction conditions resulted in branched poly (glycerol …

Biocatalyst and continuous microfluidic reactor for an intensified production of n-butyl levulinate: Kinetic model assessment

A Cordier, M Klinksiek, C Held, J Legros… - Chemical Engineering …, 2023 - Elsevier
The use of enzymes to catalyze chemical reactions has increased these recent years.
Several models have been developed to express the kinetics over these biocatalysts. The …

Lipase-mediated mechanoenzymatic synthesis of sugar esters in dissolved unconventional and neat reaction systems

R Hollenbach, A Delavault, L Gebhardt… - ACS Sustainable …, 2022 - ACS Publications
Mechanochemical and biocatalytic approaches in modern research are two major assets to
develop greener processes. In the present study, these modular tools of sustainability are …

Mechanism and kinetics of lipase-catalyzed polycondensation of glycerol and sebacic acid: Influence of solvent and temperature

GB Perin, MI Felisberti - Biomacromolecules, 2022 - ACS Publications
The mechanism for the Candida antactica lipase B (CALB)-catalyzed polycondensation of
glycerol and sebacic acid in polar solvents was proposed based on the profile of formation …

Optimization of glycolipid synthesis in hydrophilic deep eutectic solvents

R Hollenbach, B Bindereif… - … in Bioengineering and …, 2020 - frontiersin.org
Glycolipids are considered an alternative to petrochemically based surfactants because they
are non-toxic, biodegradable, and less harmful to the environment while having comparable …

Simplified method to optimize enzymatic esters syntheses in solvent-free systems: Validation using literature and experimental data

RR Sousa, ASA Silva, R Fernandez-Lafuente… - Catalysts, 2021 - mdpi.com
The adoption of biocatalysis in solvent-free systems is an alternative to establish a greener
esters production. An interesting correlation between the acid: alcohol molar ratio and …

Catalytic properties of recombinant Thermomyces lanuginosus lipase immobilized by impregnation into mesoporous silica in the enzymatic esterification of saturated …

GA Kovalenko, LV Perminova… - … Kinetics, Mechanisms and …, 2019 - Springer
Immobilization of recombinant Thermomyces lanuginosus lipase (designated as r Pichia/lip)
was carried out by moisture capacity impregnation of mesoporous silica granules followed …