Influence of reaction conditions on kumada catalytic transfer polymerization for synthesis of poly (p-phenylene) for organic semiconductors
DC Santos, TP de Paula, EB de Brito, JJR Arias… - Journal of Polymer …, 2022 - Springer
This work studied two different methodologies for the synthesis of poly (p-phenylene)(PPP)
via Kumada Catalytic Transfer Polymerization (KCPT). The first methodology varied reaction …
via Kumada Catalytic Transfer Polymerization (KCPT). The first methodology varied reaction …
Structure-reactivity relationships in organosilicon chemistry revisited
Available quantitative data of the reactivity of organosilicon compounds were subjected to
correlation analysis. As an alternative to the carbon chemistry values, the scale of steric …
correlation analysis. As an alternative to the carbon chemistry values, the scale of steric …
A novel insight into the inductive effect in silicon chemistry
A Ploom, A Tuulmets - Journal of Organometallic Chemistry, 2009 - Elsevier
A revision of quantitative literature data for the reactivity of organosilicon compounds in light
of conceptions stemmed from organic chemistry has been carried out. It has been found that …
of conceptions stemmed from organic chemistry has been carried out. It has been found that …
Quantitative substituent effects in the Grignard reaction with silanes
O Golubev, D Panov, A Ploom, A Tuulmets… - Journal of …, 2007 - Elsevier
Kinetics of reactions of ethyl-and phenylmagnesium chlorides with chlorosilanes, RMeSiCl2,
were investigated in diethyl ether under pseudo-first order conditions with a great excess of …
were investigated in diethyl ether under pseudo-first order conditions with a great excess of …
Selectivity in the grignard reaction with silanes
Selectivity problems in preparation of silanes by Grignard reaction were discussed. A
quantitative approach in terms of LFE analysis was proposed. It appeared that the inductive …
quantitative approach in terms of LFE analysis was proposed. It appeared that the inductive …
Steric parameters for substituents bound to atoms of silicon and some other elements of the third period
The kinetics of a tetraethoxysilane reaction with n-butylmagnesium chloride,
stoichiometrically monosolvated with isopropyl ether or with methyl tert-butyl ether, was …
stoichiometrically monosolvated with isopropyl ether or with methyl tert-butyl ether, was …
A kinetic view of the mechanism of the grignard reaction with alkoxysilanes
A Ploom, A Tuulmets, D Panov… - Phosphorus, Sulfur, and …, 2015 - Taylor & Francis
The kinetics of the reaction of n-butyl-and isopropylmagnesium chloride with
alkyltriethoxysilanes (RSi (OEt) 3) in diethyl ether were determined. The rate constants …
alkyltriethoxysilanes (RSi (OEt) 3) in diethyl ether were determined. The rate constants …
Synthesis and characterization of aryltriphenylsilyl ethers and crystal structure of 2,4,6-tri-methylphenyl triphenylsilyl ether
S Begeç, A Kiliç, F Yuksel, S Alataş… - Journal of Coordination …, 2013 - Taylor & Francis
Synthesis and structures of aryl triphenylsilyl ether derivatives are reported. Reactions of
chlorotriphenylsilane,(C6H5) 3SiCl (1), with sodium salts of sterically hindered phenol …
chlorotriphenylsilane,(C6H5) 3SiCl (1), with sodium salts of sterically hindered phenol …
[PDF][PDF] Kvantitatiivsete efektide uurimine silaanide reaktsioonis Grignard'i reaktiiviga
O Golubev - 2007 - core.ac.uk
Kvantitatiivsete efektide uurimine silaanide reaktsioonis Grignard’i reaktiiviga Page 1
TARTU ÜLIKOOL Füüsika-keemiateaduskond Orgaanilise ja bioorgaanilise keemia instituut …
TARTU ÜLIKOOL Füüsika-keemiateaduskond Orgaanilise ja bioorgaanilise keemia instituut …
[引用][C] Silisyum ve fosfor halojenürlerin halkalı bileşiklerle reaksiyonlarının incelenmesi
N Kan - platform.almanhal.com
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يتم تحضير الملف الاستخدام المجاني إذا كنت ترغب في الوصول الكامل إلى هذا المحتوى وقاعدة …
يتم تحضير الملف الاستخدام المجاني إذا كنت ترغب في الوصول الكامل إلى هذا المحتوى وقاعدة …