Distinct chemical factors in hydrolytic reactions catalyzed by metalloenzymes and metal complexes

LF Serafim, VM Jayasinghe-Arachchige… - Chemical …, 2023 - pubs.rsc.org
The selective hydrolysis of the extremely stable phosphoester, peptide and ester bonds of
molecules by bio-inspired metal-based catalysts (metallohydrolases) is required in a wide …

Bioinspired Catalyst Design Principles: Progress in Emulating Properties of Enzymes in Synthetic Catalysts

B Ginovska, OY Gutiérrez, A Karkamkar, MS Lee… - ACS …, 2023 - ACS Publications
Catalysis enables many aspects of modern life, including fuels, products, plastics, and
medicines. Recent advances in catalysis have enabled us to realize higher efficiencies and …

Diblock copolypeptoids: a review of phase separation, crystallization, self-assembly and biological applications

S Xuan, RN Zuckermann - Journal of Materials Chemistry B, 2020 - pubs.rsc.org
Polypeptoids are biocompatible, synthetically accessible, chemically and enzymatically
stable, chemically diverse, and structurally controllable. As a bioinspired and biomimetic …

Sequence-defined synthetic polymers for new-generation functional biomaterials

Z Deng, Q Shi, J Tan, J Hu, S Liu - ACS Materials Letters, 2021 - ACS Publications
Synthetic polymers have been extensively exploited for biomedical and pharmacological
applications, spanning from surgical devices, diagnostics, tissue engineering, regenerative …

Mechanistic Aspects of Cobalt–Oxo Cubane Clusters in Oxidation Chemistry

J Amtawong, AI Nguyen, TD Tilley - Journal of the American …, 2022 - ACS Publications
Cobalt oxides are recognized as one of the most efficient earth-abundant catalysts for
challenging oxidation chemistry, with substrates ranging from water to organic compounds …

Cooperative Intramolecular Hydrogen Bonding Strongly Enforces cis-Peptoid Folding

AW Wijaya, AI Nguyen, LT Roe… - Journal of the …, 2019 - ACS Publications
Sequence-defined peptoids, or N-substituted glycines, are an attractive class of bioispired
polymer due to their biostability and efficient synthesis. However, the de novo design of …

Development of a Systematic and Extensible Force Field for Peptoids (STEPs)

BS Harris, KK Bejagam, MD Baer - The Journal of Physical …, 2023 - ACS Publications
Peptoids (N-substituted glycines) are a class of biomimetic polymers that have attracted
significant attention due to their accessible synthesis and enzymatic and thermal stability …

Thermodynamic Basis for the Stabilization of Helical Peptoids by Chiral Sidechains

S Alamdari, K Torkelson, X Wang… - The Journal of …, 2023 - ACS Publications
Peptoids are a class of highly customizable biomimetic foldamers that retain properties from
both proteins and polymers. It has been shown that peptoids can adopt peptide-like …

Bottom-up construction of chiral metal-peptide assemblies from metal cluster motifs

PM Cheng, T Jia, CY Li, MQ Qi, MH Du, HF Su… - Nature …, 2024 - nature.com
The exploration of artificial metal-peptide assemblies (MPAs) is one of the most exciting
fields because of their great potential for simulating the dynamics and functionality of natural …

Engineering the atomic structure of sequence-defined peptoid polymers and their assemblies

S Xuan, RN Zuckermann - Polymer, 2020 - Elsevier
Peptoids are a family of sequence-defined, non-natural biomimetic polymers which show
excellent properties including good chemical and enzymatic stability and high structural …