Bio-based polyesters: Recent progress and future prospects

Q Zhang, M Song, Y Xu, W Wang, Z Wang… - Progress in Polymer …, 2021 - Elsevier
The development of sustainable and environmentally friendly polymer materials is among
the most pressing contemporary challenges for polymer science and engineering. Bio …

A review on current strategies for the modulation of thermomechanical, barrier, and biodegradation properties of poly (butylene succinate)(PBS) and its random …

MI Peñas, RA Pérez-Camargo, R Hernández, AJ Müller - Polymers, 2022 - mdpi.com
The impact of plastics on the environment can be mitigated by employing biobased and/or
biodegradable materials (ie, bioplastics) instead of the traditional “commodities”. In this …

Polybutylene succinate, a potential bio-degradable polymer: synthesis, copolymerization and bio-degradation

KS Savitha, BR Paghadar, MS Kumar… - Polymer Chemistry, 2022 - pubs.rsc.org
Poly (butylene succinate) is one of the emerging bio-degradable polymers, which has huge
potential to be employed in a wide range of applications. Furthermore, it is also recognized …

Synthesis, Crystallization, Structure Memory Effects, and Molecular Dynamics of Biobased and Renewable Poly(n-alkylene succinate)s with n from 2 to 10

PA Klonos, L Papadopoulos, M Kasimatis… - …, 2021 - ACS Publications
In this article, we synthesize five poly (n-alkylene succinate) s, P n ASs, with n= 2, 4, 6, 8,
and 10 via multi-step polycondensation methods. Next, we comparatively investigate these …

Tailoring the nucleation and crystallization rate of polyhydroxybutyrate by copolymerization

MR Caputo, C Shi, X Tang, H Sardon… - …, 2023 - ACS Publications
In the polyester family, the biopolymer with the greatest industrial potential could be poly (3-
hydroxybutyrate)(PHB), which can be produced nowadays biologically or chemically. The …

[HTML][HTML] Tunable enzymatic biodegradation of poly (butylene succinate): biobased coatings and self-degradable films

MI Penas, M Criado-Gonzalez, AM de Ilarduya… - Polymer Degradation …, 2023 - Elsevier
Biodegradation of polyesters driven by enzymes is considered as one of the most effective
way of degradation of these materials, as a way to control plastics accumulation in the …

Molecular mobility, crystallization and melt-memory investigation of molar mass effects on linear and hydroxyl-terminated poly (ε-caprolactone)

PA Klonos, ND Bikiaris, E Christodoulou, A Zamboulis… - Polymer, 2022 - Elsevier
In this work, we synthesized and investigated five linear and–OH terminated poly (ε-
caprolactone) s, PCL, prepared by ring opening polymerization. The samples cover the …

Challenging Isodimorphism Concepts: Formation of Three Crystalline Phases in Poly(hexamethylene-ran-octamethylene carbonate) Copolymers

Y Liao, RA Pérez-Camargo, H Sardon… - …, 2023 - ACS Publications
In this work, poly (hexamethylene-ran-octamethylene carbonate) copolycarbonates were
synthesized by melt polycondensation in a wide range of compositions. The copolymers …

[HTML][HTML] Structure, morphology and crystallization of isodimorphic random copolymers: Copolyesters, copolycarbonates and copolyamides

RA Pérez-Camargo, M Safari, JT Rodríguez, Y Liao… - Polymer, 2023 - Elsevier
Random copolymerization is used to prepare new polymeric materials that combine the
desirable properties of different homopolymers. The covalent bonds between the …

Recent applications of the Successive Self-nucleation and Annealing thermal fractionation technique

RA Pérez-Camargo, D Cavallo, AJ Müller - Frontiers in Soft Matter, 2022 - frontiersin.org
Successive Self-nucleation and Annealing (SSA) is a thermal fractionation technique that is
performed by Differential Scanning Calorimetry (DSC). The combination of non-isothermal …