We review here new developments in decreasing the catalyst loadings in palladium‐
catalyzed C–C bond‐formation reactions to mol ppm or mol ppb levels. This decreases the …

Palladium-catalyzed cross-couplings and related reactions have enabled many
transformations essential to the synthesis of pharmaceuticals, agrochemicals, and organic …

Reported herein is a well-defined bidentate geometry-constrained iminopyridyl cobalt
complex for an efficient and highly Markovnikov-selective hydrosilylation of alkynes …

We developed a Pd-catalyzed intermolecular reductive Heck reaction to construct Csp2–
Csp3 bonds between aryl bromides and olefins. Various styrene derivatives, acyclic and …

The simple synthesis of a family of palladates containing an imidazolium counterion is
presented. These “ate” complexes can be easily converted into well-defined palladium–N …

Pyrazole-containing compounds have been used in recent times as ligands to stabilize
metal complexes used as pre-catalysts in cross-coupling reactions. With various substituents …

The versions of Miyaura borylation and protoboration of alkynes catalyzed by low loadings
of palladium (400 mol ppm= 0.04 mol%) have been developed. These transformations have …

A protocol for selective and efficient synthesis of symmetrical and unsymmetrical m-
terphenyls is presented among aryl acetylene and DMSO in the presence of KOH and …

We developed a series of unsymmetrical CNN-palladacycles with geometry-constrained
iminopyridyl ligands, which were conveniently prepared through a simple one-pot procedure …

Heterogeneous homocoupling reactions of phenylboronic acids were greatly accelerated
via Suzuki homocoupling reactions. In this work, a tandem route was designed which firstly …